INVISTA North America S.à.r.l. v. M & G USA Corp.

951 F. Supp. 2d 604, 2013 U.S. Dist. LEXIS 88641, 2013 WL 3196770
District Court, D. Delaware·Decided June 25, 2013·No. Civ. No. 11-1007-SLR-CJB·Published·Cited by 1 cases

Opinion

MEMORANDUM OPINION

SUE L. ROBINSON, District Judge.

1. INTRODUCTION

Plaintiffs INVISTA North America S.a.r.l. and Auriga Polymers Inc.1 (collectively, “Invista”) are suing M & G USA Corporation and M & G Polymers USA, LLC (collectively, “M & G”) for infringement of United States Patent Nos. No. 7,919,159 (“the '159 patent”), 7,943,216 (“the '216 patent”), and 7,879,930 (“the '930 patent”) (collectively, “the patents-in-suit”). (D.I. 1; D.I. 7) M & G has asserted counterclaims seeking declaratory judgment of non-infringement and invalidity of the patents-in-suit. (D.I. 42) The patents-in-suit relate to plastic materials with applications in packaging for oxygen-sensitive foods and beverages. Currently before the court is claim construction, for which the court held a Markman hearing on April 19, 2013. The court has jurisdiction over this matter pursuant to 28 U.S.C. § 1338.

II. BACKGROUND

A. Technology Overview

Plastic polymers are commonly used for making food and beverage containers and offer several advantages over the use of glass or metal. They are lighter in weight, have less breakage, and can potentially lower costs. ('216 patent, col. 1:25-27)2 Polymers are synthesized by reacting monomers to form a larger polymer chain, and they can be made into bottles by a method called stretch blow molding. In stretch blow molding, a polymer resin is [608]*608typically dried, melted and extruded into preforms. (Id., col. 7:56-58) The preforms are then heated and blown-molded into bottles of desired shape and size. (Id., col. 7:62-64)

One type of polymer, polyester, has been widely used in the bottling industry for many years. Polyethylene terephthalate (“PET”) is a common example of a polyester. (Id., col. 2:34, 8:16) Polyesters can be prepared by reacting diesters (e.g., dicarboxylic ester) or diacids (e.g., terephthalic acide) with ethylene glycol (“EG”). (Id., col. 3:27-31) However, polyesters have inferior gas-barrier properties. Because they are not impervious to gas, they limit the shelf life of oxygen-sensitive foods, condiments, and beverages (such as juice, soda, or beer). (Id., col. 1:27-33)

In the prior art, it was known that the use of low-gas permeable polymers, known as partially aromatic polyamides (or “nylons”), with polyesters increases barrier properties. (Id., col. 1:31-38) Partially aromatic polyamides have non-scavenging, or “passive,” barrier properties— they restrict carbon dioxide leakage from, and oxygen intrusion into, a container by obstructing the paths of gas molecules. (Id., col. 1:21; '930 patent, col. 2:22) However, partially aromatic polyamides are not miscible — they do not mix well — with polyesters like PET, and they also give containers an undesirable yellow and hazy appearance. ('216 patent, col. 1:44^6)

It was commonly known in the art that combining a thin layer of a partially aromatic polyamide, like MXD6,3 with one or more layers of polyester in multilayer bottles increased barrier properties. (Id., col. 1:35-43; '930 patent, col. 2:18-25) This multilayer system, however, produced bottles with undesirable haze. ('216 patent, col. 1:33-35)

It was also known in the art that the addition of a transition metal catalyst, such as cobalt salt, improved the gas barrier properties of polyamide multilayer containers and blends with PET by promoting active oxygen scavenging. (Id., col. 2:32-48; '930 patent, col. 1:30-31, 1:51-5-55) As opposed to a passive barrier, this “active” barrier reacts with oxygen in the process of traversing the package barrier. ('930 patent, col. 1:33-38)

B. The Inventions and Patents-in-Suit
1. The '159 and '216 patents4

According to the patentee, no prior art disclosed a monolayer container with a desirable balance of high gas barrier properties and low yellowness and haze. ('216 patent, col. 2:55-61) The '159 and '216 patents teach compositions with increased gas bamer properties that can be used in monolayer containers and have reduced yellowness and haze. (Id., col. 2:55-61; 2:65-3:13) The inventions are useful has packaging for oxygen-sensitive foods that require a long shelf life. (Id., col. 2:55-67)

The '159 patent discloses a four-component composition. Claim 1 of the '159 patent provides:

1. A composition for containers comprising: polyester, partially aromatic polyamide, ionic compatibilizer, and a cobalt salt; wherein said ionic compatibilizer is a copolyester containing a metal sulfonate salt.

As discussed, the partially aromatic polyamide provides a passive barrier. The [609]*609cobalt salt is a transition metal catalyst that “activates” the partially aromatic polyamide to form an active barrier that scavenges oxygen, thereby improving barrier properties. The patentee reports that the ionic compatibilizer allows a “synergistic reduction” in yellowness and haze and “surprisingly” increases barrier properties even further. ('159 patent, col. 5:22-25, 9:58-61)

The '216 patent is a division of the '159 patent and shares the same specification. (See '216 patent, col. 1:8-9) The '216 patent discloses a three-component composition. Claim 1 of the '216 patent recites:

1. A composition for containers comprising:
a copolyester comprising a metal sulfonate salt;
a partially aromatic polyamide; and a cobalt salt.

The composition of the '216 patent differs from that of the '159 patent in that it replaces the polyester and ionic compatibilizer components and recites, in their place, “a copolyester comprising a metal sulfonate salt.” The other claims of the '216 and '159 patents recite more specific compositions, as well as articles and containers made from the compositions.

2. The '930 patent5

Invista is also asserting indirect infringement of claims 1, 3-6, 8,10, and 11 of the '930 patent, which relates to colored oxygen scavenging polymers and articles made from such polymers, such as green, blue, or amber bottles. ('930 patent, col. 1:7-8, 2:20) In the prior art, it was not problematic to use colorants because there would be no reaction between the colorant, which was added to the non-scavenging (or passive barrier) layers and the transition metal catalyst, which was contained in the oxygen scavenging (or active barrier) layer. (Id., col. 2:20-25) However, in mono-layer articles, such as those taught in the '159 and '216 patents, the colorant is intimately mixed in a melt phase with the transition metal catalyst. (Id., col. 2:35-38) Some colorants deactivate the transition metal catalyst after melt blending, which makes the transition metal catalyst less effective as a catalyst. (Id., col. 2:32-34)

The '930 patent relates to the use of certain colorants that do not completely deactivate the catalyst and, thus, are suitable for use with a transition metal catalyst in monolayer scavenging systems. (Id., col.

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INVISTA North America S.à.r.l. v. M & G USA Corp., 951 F. Supp. 2d 604, 2013 U.S. Dist. LEXIS 88641, 2013 WL 3196770 (D. Del. 2013).

951 F. Supp. 2d 604 (INVISTA North America S.à.r.l. v. M & G USA Corp.) — published by Counsel Stack Legal Research, free access to 12M+ legal documents.

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