Rem-Cru Titanium, Inc. v. Watson

147 F. Supp. 915, 112 U.S.P.Q. (BNA) 88, 1956 U.S. Dist. LEXIS 4161
CourtDistrict Court, District of Columbia
DecidedDecember 21, 1956
DocketCiv. A. 1699-54
StatusPublished
Cited by4 cases

This text of 147 F. Supp. 915 (Rem-Cru Titanium, Inc. v. Watson) is published on Counsel Stack Legal Research, covering District Court, District of Columbia primary law. Counsel Stack provides free access to over 12 million legal documents including statutes, case law, regulations, and constitutions.

Bluebook
Rem-Cru Titanium, Inc. v. Watson, 147 F. Supp. 915, 112 U.S.P.Q. (BNA) 88, 1956 U.S. Dist. LEXIS 4161 (D.D.C. 1956).

Opinion

CURRAN, District Judge.

This is a civil action brought by the plaintiff, Rem-Cru Titanium, Inc., against the defendant, Robert C. Watson, Commissioner of Patents, ■ pursuant to Title 35, Section 145 of the United States Code, to authorize the Commissioner of Patents to issue to the plaintiff letters patent, containing Claims 5, 6, 7 and 8 of an application, Serial No. 187,370, entitled “Titanium Alloy”, filed September 28, 1950, by Robert I. Jaffee, Horace R. Ogden and Daniel L. Maykuth. This application has been assigned to Rem-Cru Titanium, Inc., plaintiff herein. Claims 5 and 6 were withdrawn by plaintiff at the trial, leaving Claims 7 and 8 for consideration by the Court.

*916 The subject matter of the application is an alloy of titanium and aluminum, in which the aluminum content is present within a certain range of proportions, namely, in the amount of 34% to 46% by weight of the total alloy. The specification discloses that titanium alloys with the indicated proportions of aluminum have a single phase, face centered, tetragonal microstructure. Further, the specification indicates that these alloys maintain their room temperature hardness at temperatures as high as 1250°C or 2300°F and are resistant to oxidation at elevated temperatures. The claims describe the titanium alloy by percentage range of aluminum and by reference to the alloy's ability to maintain its hardness when heated and its high resistance to oxidation, or by reference to these advantages and additional reference to crystalline structure and ultimate strength.

Claims 7 and 8 were rejected by the Examiner as being unpatentable over the United States patent to Gray, No. 2,299,228, dated October 20, 1942; the Hansen publication, “Aufban der Zweistofflegierunger” (1943); and Science Abstracts, Section A, Physics, Vol. VI, 1903. These rejections were affirmed, by the Board of Appeals of the Patent Office.

The more specific of the two claims is Claim 8, its essential elements being: a titanium base alloy containing about 34-46% of aluminum; characterized in having a single phase, face centered, tetragonal microstructure; an ultimate strength at room temperature of at least 126,000 psi (pounds per square inch); being highly resistant to oxidation at elevated temperatures; and maintaining substantially its room temperature hardness at elevated temperatures as high as 1250°C. Claim 7 covers the same range of alloys and their characteristics but omits recitation of the microstructure and the ultimate strength thereof.

Both claims are directed to a critical range of aluminum content which plaintiff contends defines a new alloy product, having the desired properties of high resistance to oxidation at elevated temperatures and maintenance of room temperature hardness at elevated temperatures.

Is there any teaching in the prior art of either the existence of this critical range of titanium.aluminum alloys, or of the nature of the highly desirable characteristics as set forth in the application here, or of the existence of the single phase microstructure specified in Claim 8, which is uniform throughout this critical range of alloys?

The Gray Patent

The patent of Gray describes the preparation of electric condensers by (a) pressing or agglomerating a multitude of metallic particles to form a porous spongy body, (b) covering or coating the surfaces of the body surrounding the pores with a dielectric layers, such as an oxide film, and (c) filling the pores of the body with a solid electrolyte. The patent states that the metallic particles may be “of the same composition or mixtures of two or more kinds of different composition or alloys.” Gray describes the use of solid solutions or alloys of two or more materials:

“The skeleton metal can also be made, as mentioned above, of solid solutions or alloys of two or more metals. If one mixes e. g. approximately 85% to 95% aluminum with 15% to 5% beryllium and heats the mixture up to about 900° to 1050 °C. then these metals form a melt which upon cooling forms a solid solution or mixed crystals. The two metals do not enter into a chemical combination but form in the main an alloy. Such an alloy is thereafter com-minuted, shaped and fritted at a temperature of about 640° to 700°C. The skeleton thus obtained is then oxidized at the temperatures below the fritting temperature, and a dense and strong dielectric layer is obtained of which the dielectric constant lies above that of the aluminum oxide due to the presence of beryllium oxide.
“Titanium has the property to form an oxide possessing a very high *917 dielectric constant. By compounding it e. g. with aluminum, an aluminum-titanite AITi, is obtained, which can be used for making a condenser in any way described above. The dielectric oxide layer produced on such a skeleton has a dielectric constant which lies considerably above that of aluminum oxide alone though below that of titanium oxide alone.”

The Board held, with respect to the recitation of the properties of the alloy in the claims, that since the Gray alloy falls within the range of alloys recited in the claims, it is fair to assume that it possesses the same properties as the plaintiff’s alloys.

Hansen Publication

It is stated in this publication that Guillet assumed the existence of the compound AI3 Ti2 (54.2% Ti.) and that Weiss-Kaiser found the same compound on repeating Manchot-Richter experiments. The Patent Office held that this statement constitutes the disclosure of an alloy which is within the range of the alloys claimed by the plaintiff and which, therefore, negatives novelty in this range of alloys.

Science Abstracts

“ ‘Titanium alloys — The mixture of A1 and TÍO2 only inflames after heating to 600°, and to obtain an ingot or alloy it is necessary to superheat the top of the mixture by means of a jet of oxygen. Compounds isolated were TiALi and TÍ203 (or possibly TiAl analogous to SnAl)”’.

The Patent Office held that admitting, arguendo, that Guillet did not produce the alloy AI3TÍ2 by the method used by him, the fact remains that he disclosed this alloy and that this disclosure per se is insufficient to negative invention in the alloy.

A reading of these prior arts disclosures reveals an absence of any teaching of the new alloy product claimed herein. There is no mention of a titanium-aluminum alloy having the claimed properties of high oxidation resistance and the retention of hardness at elevated temperatures, or of high ultimate strength at atmospheric temperature, or of an alloy having the claimed unique single phase face centered microstructure, or of the critical nature of the claimed range of 34-46% aluminum in a titanium-aluminum alloy which defines a new product. There are isolated references which mention by name only AITi and AI3TÍ2 which happened to contain aluminum within the range of the claims in issue. There is no question that if the prior art shows a range which includes the range claimed in the instant application, in the absence of the production of a different product by plaintiff, plaintiff is not entitled to a patent.

The defendant takes the position that the aluminum titanite (AITi) alloy of Gray falls within the range of 34-46% aluminum alloys described in the claim.

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147 F. Supp. 915, 112 U.S.P.Q. (BNA) 88, 1956 U.S. Dist. LEXIS 4161, Counsel Stack Legal Research, https://law.counselstack.com/opinion/rem-cru-titanium-inc-v-watson-dcd-1956.