In re Johnson

558 F.2d 1008, 194 U.S.P.Q. (BNA) 187, 1977 CCPA LEXIS 140
CourtCourt of Customs and Patent Appeals
DecidedJune 16, 1977
DocketPatent Appeal No. 76-643
StatusPublished
Cited by15 cases

This text of 558 F.2d 1008 (In re Johnson) is published on Counsel Stack Legal Research, covering Court of Customs and Patent Appeals primary law. Counsel Stack provides free access to over 12 million legal documents including statutes, case law, regulations, and constitutions.

Bluebook
In re Johnson, 558 F.2d 1008, 194 U.S.P.Q. (BNA) 187, 1977 CCPA LEXIS 140 (ccpa 1977).

Opinions

MARKEY, Chief Judge.

This appeal is from the decision of the Patent and Trademark Office (PTO) Board of Appeals affirming the rejection under 35 U.S.C. §§ 102 or 103 (the rejection also raises a written description issue under 35 U.S.C. § 112, first paragraph) of claims 1-9, 64, and 68-70 and the rejection under 35 U.S.C. § 112, first paragraph (enablement) and second paragraph (indefiniteness), of claims 64 and 68-72 in appellants’ application No. 230,091 filed February 28, 1972 (the 1972 application) for “Polyarylene Po-lyethers.” 1 The 1972 application is a continuation-in-part of three earlier applications, the earliest being application No. 295,519 filed July 16,1963 (the 1963 application). We reverse.

The Invention

The invention is in the field of polymer chemistry and more specifically relates to linear thermoplastic polyarylene polyether polymers composed of recurring units having the general formula-O-E-O-E’where O represents an oxygen atom,2 E represents the residuum of a dihydric phenol 3 compound, and E' represents the resid[1010]*1010uum of a benzenoid compound having one or more inert electron withdrawing groups 4 in the ortho5 or para6 positions to the valence bonds and where both E and E' are bonded to the ether oxygens through aromatic carbon atoms.

Appellants describe a method of synthesizing these polymers by reacting a double alkali metal salt of a dihydric phenol with a dihalobenzenoid compound in the presence of certain solvents under substantially anhydrous reaction conditions.

The 1972 application includes the following disclosure with respect to the electron withdrawing group found in E' and in the E' precursor compound, that is, in the compound which is the predecessor of E' in the above general formula (we have designated paragraphs [A] and [B] and have added emphasis thereto):

Any electron withdrawing group can be employed as the activator group in these compounds. It should be, of course, inert to the reaction, but otherwise its structure is not critical. Preferred are the strong activating groups such as the sulfone group
benzenoid nuclei as in the 4,4'-dichloro-diphenyl sulfone and 4,4'-difluorodiphenyl sulfone, although such other strong withdrawing groups hereinafter mentioned can also be used with equal ease.
The more powerful of the electron withdrawing groups give the fastest reactions and hence are preferred. It is further preferred that the ring contain no electron supplying groups on the same benzenoid nucleus as the halogen; however, the presence of other groups on the nucleus or in the residuum of the compound can be tolerated. Preferably, all of the substituents on the benzenoid nucleus are either hydrogen (zero electron withdrawing), or other groups having a positive sigma * value, as set forth in J.F. Bunnett in Chem.Rev. 49 273 (1951) and Quart.Rev., 12, 1 (1958). See also Taft, Steric Effects in Organic Chemistry, John Wiley & Sons (1956), chapter 13; Chem. Rev., 53, 222; JACS, 74, 3120; and JACS, 75, 4231.7
The electron withdrawing group of the dihalobenzenoid compound can function either through the resonance of the aromatic ring, as indicated by those groups having a high sigma * value, i.e., above about + 0.7 or by induction as in perfluo-ro compounds and like electron sinks.
[A]
Preferably the activating group should have a high sigma * value, preferably above 1.0, although sufficient activity to promote the reaction is evidenced in those groups having a sigma value above 0.7, although the reaction rate with such a low powered electron withdrawing group may be somewhat low.
The activating group can be basically either of two types:
(a) monovalent groups that activate one or more halogens on the same ring as a nitro group, phenylsulfone, or alkylsul-fone, cyano, trifluoromethyl, nitroso, and hetero nitrogen as in pyridine.
[1011]

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Bluebook (online)
558 F.2d 1008, 194 U.S.P.Q. (BNA) 187, 1977 CCPA LEXIS 140, Counsel Stack Legal Research, https://law.counselstack.com/opinion/in-re-johnson-ccpa-1977.