In re Smith

458 F.2d 1389, 59 C.C.P.A. 1025, 173 U.S.P.Q. (BNA) 679, 1972 CCPA LEXIS 324
CourtCourt of Customs and Patent Appeals
DecidedMay 18, 1972
DocketNo. 8590
StatusPublished
Cited by36 cases

This text of 458 F.2d 1389 (In re Smith) is published on Counsel Stack Legal Research, covering Court of Customs and Patent Appeals primary law. Counsel Stack provides free access to over 12 million legal documents including statutes, case law, regulations, and constitutions.

Bluebook
In re Smith, 458 F.2d 1389, 59 C.C.P.A. 1025, 173 U.S.P.Q. (BNA) 679, 1972 CCPA LEXIS 324 (ccpa 1972).

Opinion

Lane, Judge.

This appeal is from the decision of the Board of Appeals sustaining the examiner’s rejection of claims 1, 2,12-18, 20 and 21 of appellant’s application, Serial No. 430,468, filed February 4, 1965, for “Glossy Emulsion Coating Compositions Containing Surface Treated Pigments of Oilophilic Nature and Method.” This application is asserted to be a continuation of an application filed in 1956,1 which was a continuation-in-part of a 1951 application,2 which in turn was a continuation-in-part of Serial No. 774,897, filed September 18, 1947. We affirm the board’s decision.

The Iwoention

The invention is directed to the compounding of a glossy water base emulsion paint. In his brief before this court, appellant distinguishes [1027]*1027between single phase, oil base paints and dual phase, water base emulsion paints wherein there is a continuous phase of water in which globules of oil are suspended. By “oil” is meant “those natural and synthetic fluid organic water insoluble compounds commonly used as a whole or part of the vehicle or binder in coating compositions.’’ Whereas oil base paints are said to be naturally glossy, water base emulsion paints tend to be “flat.” Various advantages are claimed for water base paints, and the object of this invention was to produce a glossy water base emulsion paint.

Appellant postulates that the reason for flatness in a water base paint is “the fact that it contains two phases, the water phase preferentially wetting some of the pigment so that some pigment is contained in the volatile water phase.” The concept underlying the present invention was the appreciation that “if the pigment used in these paints could be surface coated in such a way that it would be wholly wetted by the oil phase and not be permitted to migrate into the water phase,” the problem would be solved.

The claims reflect this approach. Claims 1 and 2 are drawn to an emulsion coating composition having a continuous water phase and a discontinuous oil phase dispersed therein. The pigment is dispersed in the discontinuous oil phase and is maintained in that phase as a result of a surface coating of an organic compound which l'enders the pigment “oilophilic,” i.e., having an affinity for oil, and, particularly, having a preferential affinity for oil as compared to water. The organic compounds with which the pigment may be coated are described in the specifications as follows:

[They] are monomeric organic compounds characterized by at least one non-polar organic hydrophobic group containing at least eight carbon atoms in a hydrocarbon structure which in the form of its monoearboxylie acid is soluble in oleoresinous varnishes and insoluble in water, and at least one polar group preferably selected from the class consisting of carboxylic acids, salts of said car-boxylic acids, esters of said carboxylic acids and cationic ammonium and amine surface active groups containing an ionizable negative radical of a water soluble acid. Such polar groups are effective in causing said organic compounds to adhere to the pigment surface, especially where the latter are hydrophilic.

Claim 1, subdivided for convenience, reads as follows:

1. An emulsion coating composition comprising essentially a continuous aqueous phase and a discontinuous water insoluble oil phase containing dispersed in said discontinuous phase a pigment which is surface coated with an organic compound effective to render said pigment oilophilic, said organic compound being a monomeric organic compound characterized by at least one non-polar organic hydrophobic group containing at least 8 carbon atoms in a hydrocarbon structure, which group in the form of its monoearboxylie acid is soluble in oleoresinous varnishes and insoluble in water, and at least one polar group, said oi’ganic com[1028]*1028pound adhering to said pigment surface when said coated pigment is emulsified, said coating having been applied to said pigment prior to emulsification thereof and prior to dispersion of said pigment in said oil phase, and said discontinuous pigmented phase being capable of forming a continuous solid glossy film when dried.

Claim 2 further defines the organic compound by the general formula:

where R is an organic radical containing 8 to 86 carbon atom® in a hydrocarbon structure, X is an inorganic cation, and n is a whole number from 1 to 2 * * *.

A series of composition claims more limited with respect to the pigment and the organic compound with which it is coated were allowed by the examiner.

The process of making the composition is also claimed. Claim 12, which is representative of the process claims on appeal, reads in pertinent part as follows:

12. A process of preparing emulsion coating compositions comprising essentially a continuous aqueous phase and a discontinuous -water insoluble oil phase containing a pigment dispersed in said discontinuous phase which- comprises surface coating a pigment with an organic compound effective to render said pigment oilophilic and adding water to said pigment, thereafter adding an oil phase and emulsifying said surface coated pigment to form a water-in-oil, pigment-in-oil emulsion and converting said water-in-oil pigment-in-oil emulsion to a pigment-in-oil, oil-in-waiter emulsion * * *.

The remaining process claims, 13-18, 20 and 21, define the method in varying degrees of specificity. Several process claims limited to a specific pigment and organic compound were allowed.

The Refer ewes

Baldwin3 discloses modifying the surface energy characteristics of a pigment by “causing precipitated suspensions of water repellant metallic organic compounds to become adherent upon the surface of the pigment in the form of a thin film covering each pigment particle.” Among the coating compounds disclosed are those used by appellant. The patentee was primarily concerned with improving pigments for use in a variety of systems, hut specific advantages of pigments made by the disclosed method are' stated to be “smoother and glossier paints * * *.”

[1029]*1029Iliff et al. (Iliff) ,4 a patent issued on May 4,1948, on an application filed April 11, 1944, involves aqueous emulsion coating composition. Patentees state:

[Djifficulties are encountered in producing materials which produce glossy films or coatings and which possess satisfactory stability in this respect. The difficulty appears to be due to a tendency for the white pigment (titanium dioxide) to migrate from the oil phase into the external aqueous phase of the emulsion resulting in instability with respect to producing glossy films or coatings.
* 4 * * * * *
This invention therefore presents as the principal object means for producing stable white or tinted emulsion coating compositions which will produce glossy films.
$ $ * $ ‡ *
These objects are accomplished in the present invention by incorporating, as the principal pigment in the composition, titanium dioxide which has been treated (as hereinafter described) to impart to it organophylie properties with respect to its action in the aqueous resin emulsion vehicle.

Iliff et al.

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Bluebook (online)
458 F.2d 1389, 59 C.C.P.A. 1025, 173 U.S.P.Q. (BNA) 679, 1972 CCPA LEXIS 324, Counsel Stack Legal Research, https://law.counselstack.com/opinion/in-re-smith-ccpa-1972.