Application of Walter L. Borkowski and John J. Van Venrooy

422 F.2d 904, 57 C.C.P.A. 946
CourtCourt of Customs and Patent Appeals
DecidedMarch 12, 1970
DocketPatent Appeal 8214
StatusPublished
Cited by61 cases

This text of 422 F.2d 904 (Application of Walter L. Borkowski and John J. Van Venrooy) is published on Counsel Stack Legal Research, covering Court of Customs and Patent Appeals primary law. Counsel Stack provides free access to over 12 million legal documents including statutes, case law, regulations, and constitutions.

Bluebook
Application of Walter L. Borkowski and John J. Van Venrooy, 422 F.2d 904, 57 C.C.P.A. 946 (ccpa 1970).

Opinion

RICH, Acting Chief Judge.

This appeal is from the decision of the Patent Office Board of Appeals affirming the rejection of claims 7-12 of application serial No. 144,221, filed October *906 10, 1961, entitled “Preparation of Oxygenated Hydrocarbons.’’ No claim is allowed.

The claimed invention is a process for producing oxygenated hydrocarbons such as alcohols, glycols, aldehydes, and acids by reacting hydrocarbons with ferric chloride in vapor phase and hydrolyzing the resulting chlorohydrocarbon. The reaction of ferric chloride with hydrocarbons is commonly referred to in the art as “ferrichlorination.”

The following drawing from appellants’ specification is a schematic illustration of the process:

*907 When read with reference to this drawing, claim 7 sufficiently describes the process for the purposes of this opinion : 1

7. Method of preparing oxygenated hydrocarbon which comprises:
(a) feeding hydrocarbon in vapor phase at an intermediate level into a reactor maintained at a temperature in the range of 315-500°C., said hydrocarbon being a vapor at the selected reaction temperature and said reactor containing beneath the level of hydrocarbon introduction a bed of iron compounds comprising a ferrous chloride mass in its upper part and a ferric oxide mass in its lower part,
(b) feeding gaseous ferric chloride into said reactor and reacting it with the hydrocarbon above said bed, whereby chlorination of hydrocarbon occurs with the formation of by-product hydrogen chloride and the ferric chloride is reduced to solid ferrous chloride which falls downwardly to said bed,
(c) removing a mixture of chlorohydrocarbon and hydrogen chloride from the upper part of said reactor,
(d) recovering hydrogen chloride from the mixture,
(e) introducing the hydrogen chloride into the bed at a level near the top of the ferric oxide mass,
(f) passing oxygen into the ferric oxide mass beneath the level of introduction of the hydrogen chloride,
(g) flowing said oxygen upwardly through the bed and in contact with the ferrous chloride, whereby the ferrous chloride is continuously converted in part to gaseous ferric chloride and in part to ferric oxide,
(h) removing ferric oxide from the bottom of said reactor,
(i) contacting said chlorohydrocarbon with water at a temperature in the range of 100-200°C. and in the presence of the removed ferric oxide, whereby the chlorohydrocarbon is hydrolyzed to oxygenated hydrocarbon and the ferric oxide is converted to hydrated ferric chloride,
(j) dehydrating the ferric chloride,
(k) and recycling the dehydrated ferric chloride to said reactor in amount substantially equivalent to the ferric oxide removed therefrom.

Claim 8 depends from claim 7 and recites a preferred temperature range of 350-425°C. for step (a); claims 9 and 10 depend, respectively, from claims 8 and 7 and recite a preferred temperature range of 120-160°C. for step (i); and claims 11 and 12 each depend from claim 7 and require, respectively, that the “hydrocarbon” be “methane” and “ethane.”

The examiner rejected claims 7-12 “as based on an insufficient disclosure under 35 U.S.C. 112” and claims 7-10 as failing to “particularly point out and distinctly claim the invention as required by 35 U.S.C. 112.” There is no art rejection.

With respect to the first rejection, the examiner was of the opinion that appellants’ description of their invention “is not such that it would enable one skilled in the art to practice the present invention, particularly with reference to the chlorination step.” He mentioned, “relative amounts of the ‘hydrocarbon’ ” and “magnitude of reaction times” as two parameters which appellants should have disclosed more fully and, while acknowledging that a specification need not “read as instructions to a technician” and that “[pjerhaps one might after a few hours of experimentation, determine how to carry out and *908 control the chlorination of the simplest hydrocarbon, methane,” the examiner stated:

But, the whole purpose of Section 112 is to obviate the necessity for such experimentation. Moreover, the conditions are obviously not the same for methane as they are for the myriad of other hydrocarbons contemplated and urged to be suitable for use in the instant process.

Sustaining this rejection, the board stated, inter alia:

The Examiner has pointed to the possible variations in the time of chlorination, probably because this is a demonstratably [sic] variable and important parameter. The disclosure, though, is no more deficient in this respect than with respect to any other of its values which would help to illustrate the “mode of operation” in which appellants believe their invention to lie. Appellants do not believe that the time of chlorination is a critical aspect of their process and, probably, if you consider this as a single parameter they are correct in this, but the asserted novelty in the mode of operation which invites a careful balance of a number of distinct reactions makes illustration particularly necessary. Desirably and necessarily, such illustration should provide an exem-. plary correlation of the times of reaction, rates of reactant, feed and material removal (chlorinated product, ferric oxide, HC1, etc.). This would inform a man skilled in the art of the actual feasibility of appellants’ process, and provide some sort of jumping off place in a plunge into the unknown when planning a series of experiments from which the necessary operating parameters of the process may be determined.

The “exemplary correlation” which the board considered necessary would appear to be nothing more nor less than a specific working example. However, as we have stated in a number' of opinions, 2 a specification need not contain a working example if the invention is otherwise disclosed in such a manner that one skilled in the art will be able to practice it without an undue amount of experimentation. Here, while it may be that an “exemplary correlation” of parameters such as times of reaction and rates of reactant feed and product removal would give the worker in the art some useful information and provide a “jumping off place,” we see no basis for concluding that without such information the worker in the art would not be enabled by the specification to practice the invention, i. e., to “balance” the several reactions involved in appellants’ process. The “few hours” experimentation mentioned by the examiner certainly would not seem to be an undue amount of time considering the nature of the claimed invention.

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422 F.2d 904, 57 C.C.P.A. 946, Counsel Stack Legal Research, https://law.counselstack.com/opinion/application-of-walter-l-borkowski-and-john-j-van-venrooy-ccpa-1970.