In re Eickmeyer

602 F.2d 974, 202 U.S.P.Q. (BNA) 655, 1979 CCPA LEXIS 224
CourtCourt of Customs and Patent Appeals
DecidedJuly 19, 1979
DocketAppeal No. 79-525
StatusPublished
Cited by13 cases

This text of 602 F.2d 974 (In re Eickmeyer) is published on Counsel Stack Legal Research, covering Court of Customs and Patent Appeals primary law. Counsel Stack provides free access to over 12 million legal documents including statutes, case law, regulations, and constitutions.

Bluebook
In re Eickmeyer, 602 F.2d 974, 202 U.S.P.Q. (BNA) 655, 1979 CCPA LEXIS 224 (ccpa 1979).

Opinion

MILLER, Judge.

This is an appeal from the decision of the Patent and Trademark Office (“PTO”) Board of Appeals (“board”), rejecting claims 28, 31, 34-37, and 40.1 We reverse.

BACKGROUND

The Invention

Appellant’s invention relates to a high temperature, catalyzed, absorption-desorption process for selectively removing acid gases (e. g., carbon dioxide and hydrogen sulfide) from gaseous mixtures, as in the purification of natural gas and hydrogen streams employed for making ammonia. The absorption solution, which includes a potassium salt {eg., potassium carbonate) and a minor amount of an amine catalyst {eg., an alkanolamine or ethylene polyamine), is contacted at elevated temperatures with the gas stream to be purified. The solution absorbs the objectionable acid gases and is then regenerated, for recycling in the continuous process, by steam stripping the acid gases from the. absorption solution. Appellant allegedly discovered that use of the defined amines in conjunction with a carbonate absorption solution at elevated temperatures is precisely contrary to the predicted results2 in that a highly catalyzed acid gas absorption solution results. Appellant’s claims require “an elevated temperature of at least 56° C.” during the absorption process. Claims 28 and 34 are typical:

28. An absorption-desorption process for removing acid gases such as CO2 or H2 S from gaseous mixture containing such acid gases, comprising the step of:

contacting said gaseous mixture with a hot aqueous solution comprising from about 15 to 40% by weight of a potassium salt selected from the group consisting of potassium carbonate, potassium borate and mixtures thereof and a minor amount of an amine selected from the group consisting of the alkanolamines and the ethylene polyamines in an absorption stage to thereby catalyze the absorption of said acid gases from said gaseous mixtures;
maintaining the aqueous solution at an elevated temperature of at least about 56° C. during contact with said gaseous mixture;
regenerating the hot aqueous solution containing said absorbed acid gas in a regeneration stage by steam stripping [976]*976at least a portion of said acid gas therefrom; and
recycling at least a portion of said regenerated solution for further contact with said gaseous mixture while maintaining said solution at a temperature of at least 56° C.
34. The process of Claim 28 wherein said aqueous solution is contacted with said gaseous mixture in a two-stage absorber.

The Prior Art

The examiner relied upon Mayland3 for its disclosure of the use of specified amines (monoethanolamine, diethanolamine, and mixtures thereof) to catalyze a carbonate absorption process for removing carbon dioxide from gaseous mixtures. Regarding the operating temperature of the process, the Mayland specification states:

The rate of absorption and desorption of CO2 in carbonate solutions is relatively slow. At ambient temperatures equipment so large as to be non-commercial would be required to provide sufficient time of contact. Operating at elevated temperatures in the 220° to 240° F. [104°-116° C] range [which is generally about the boiling point of the carbonate absorption solution in the regenerator], the rates are improved considerably but the equipment is still somewhat large for a given service compared to other competitive processes.

Nevertheless, none of the Mayland claims recites any qualitative or quantitative temperature limitation, the significance of which will later appear. Claim 1 is illustrative:

1. In a regenerative process for purifying gaseous mixtures by removing carbon dioxide therefrom, in which process the gaseous mixtures are brought into intimate contact with a solution of potassium carbonate whereby carbon dioxide is absorbed from said gaseous mixtures with the consequent conversion of potassium carbonate to potassium bicarbonate, the concentration of the said solution being equivalent to that of a water solution containing substantially 18% to substantially 40% of potassium carbonate, the step of maintaining in the solution a content of substantially 0.5% to 2% of an amine chosen from a group consisting of monoethanolamine and diethanolamine and mixtures thereof, whereby to increase the efficiency of the process.

Acting pursuant to 37 CFR 1.196(b), the board relied upon two further references: a British patent4 and a U. S. patent to Benson.5 The British patent discloses a carbonate absorption process, which is catalyzed by ethanolamine, for removing carbon dioxide from gas mixtures and is similar to the process disclosed in Mayland. Benson was cited for its teaching of a split-stream technique in an analogous gas purification process.

Proceedings Below

Concurrent with the filing of the application on appeal, appellant filed a notice under 37 CFR 1.205(b) with a supporting explanation and affidavits in order to provoke an interference with Mayland.6 In the first [977]*977office action, the examiner refused to institute an interference, stating:

The limitation of 18-40% in the patent claim is not deemed an immaterial limitation. It is the broadest range disclosed in the patent specification. No basis is found in applicant’s disclosure for the claimed amine concentration in a potassium carbonate solution. The affidavit showing of 2.3% amine in a 14.7% solution does not antedate the Mayland patent and no basis is perceived for institution of interference proceedings.

Thereafter, appellant amended his claims in response to numerous prior art rejections made by the examiner and submitted an affidavit under 37 CFR 1.131 (hereinafter “131 affidavit”) to antedate the filing date of Mayland.

In the next office action, the examiner declared that the 131 affidavit of applicant “has been considered but may not be utilized to antedate the patent to Mayland as both applicant and Mayland are claiming substantially the same invention.” The examiner did not contest the sufficiency of the 131 affidavit showing — only the applicability of the affidavit. During subsequent office actions, all rejections were withdrawn except that claims 28, 31, 34-37, and 40 were rejected as anticipated by Mayland under 35 U.S.C. § 102. The examiner adhered to his previous position, saying:

The claims of Mayland are of the Jepson type, however, and refer to a regenerative process of removing carbon dioxide from gases utilizing a carbon solution wherein the improvement is the maintaining [of, sic] the carbonate solution [with, sic] a specified amount of an amine.

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Bluebook (online)
602 F.2d 974, 202 U.S.P.Q. (BNA) 655, 1979 CCPA LEXIS 224, Counsel Stack Legal Research, https://law.counselstack.com/opinion/in-re-eickmeyer-ccpa-1979.