Chemical Separation Technology, Inc. v. United States

71 Fed. Cl. 135, 2006 U.S. Claims LEXIS 149, 2006 WL 1645024
CourtUnited States Court of Federal Claims
DecidedJune 14, 2006
DocketNo. 97-21C
StatusPublished

This text of 71 Fed. Cl. 135 (Chemical Separation Technology, Inc. v. United States) is published on Counsel Stack Legal Research, covering United States Court of Federal Claims primary law. Counsel Stack provides free access to over 12 million legal documents including statutes, case law, regulations, and constitutions.

Bluebook
Chemical Separation Technology, Inc. v. United States, 71 Fed. Cl. 135, 2006 U.S. Claims LEXIS 149, 2006 WL 1645024 (uscfc 2006).

Opinion

OPINION

ALLEGRA, Judge.

Chemical Separation Technology, Inc. (CST) and Sanford M. Stevenson (Mr. Stevenson) seek compensation from the United States, under 28 U.S.C. § 1498(a), for the unlawful use of two of their patents — U.S. Patent No. 4,749,497 (the ’497 patent) and U.S. Patent No. 5,370,800 (the ’800 patent)— both of which relate to the treatment of waste water. In this opinion, the third in a series, the court analyzes whether the government unlawfully used the patents at the Summitville Mine site in southern Colorado, and thereby owes plaintiffs damages. After carefully considering the record, the parties’ briefs, and the closing arguments herein, the court finds that there was no infringement and that plaintiffs’ case, therefore, must be dismissed.

I. FINDINGS OF FACT1

Based upon the record, including the parties’ stipulations, the court finds as follows:

A. Background

CST, an Idaho corporation, and its president and major shareholder, Mr. Stevenson, own the ’497 patent and the ’800 patent, the methods embodied in which are used in an apparatus constructed by CST known as the “portable interim treatment system” or “PIT System.” Using a series of chemical agents, the PIT System precipitates and removes hazardous minerals and compounds from acidic mine waste water. A critical feature of the “method” is the addition of cationic and/or anionic polymers2 to the polluted water, thereby causing the precipitated minerals to clump together (flocculate). To better understand this method, a short discussion of acid mine drainage (AMD) and the processes commonly used to treat it follows.

When water and oxygen react with rocks containing sulfur-bearing minerals (such as iron pyrite, FeSe2), AMD, also referred to as acid mine leachate or mine leachate, is formed. One of the experts summarized this chemical reaction, as follows, in his report—

The process is initiated by the oxidation of sulfur in the pyrite by dissolved oxygen in the water, releasing iron in the ferrous form (Fe2+) and sulfur as sulfate (SC^2-). Hydrogen ions (H+) that increase the acidity of the solution and lower the pH are also produced. If the ferrous iron in the AMD solution is oxidized by oxygen ..., ferric iron (Fe3+) is formed that can oxidize, like oxygen, the sulfur in the pyrite to form more sulfate, ferrous iron, and acid. This essentially self-propagating part of the overall reaction that creates AMD tends to be catalyzed by iron-oxidiz[138]*138ing bacteria, making the AMD generation process quite complicated.

AMD routinely contains not only iron species and sulfuric acid, but also significant amounts of calcium and aluminum; heavy metals such as copper, lead and mercury; and anionic forms of arsenic and chromium. Some of these materials are leached from minerals that come into contact with AMD, with the pH of the AMD varying in accordance with the acid neutralizing properties (or lack thereof) of such minerals.3

AMD must be treated before being discharged into the environment. That treatment typically includes the following steps: neutralization of the acidity, including increasing the pH; removal of toxic materials, such as copper and arsenic; and removal of elements such as iron and aluminum that form precipitates that destroy aquatic habits and diminish water quality. As described in an EPA Design Manual in the record—

When metals precipitate from wastewater, the particles they form vary in size but are no longer part of the liquid; a liquid containing such solid particles becomes a “suspension;” the term ‘colloidal suspension’ is used when the solid particles are very small and difficult to settle. Most of the precipitated metals in suspension will naturally settle, or form a sediment, under the force of gravity. This process of settling, or clarification, separates the precipitated metals from the waste water, and the treated water is then discharged. This treated water is called “supernatant” or “overflow,” and the sediment is called “sludge” or “underflow.”

Because the precipitation of metals involves reactions with oxygen, hydrogen, water, and other constituents of wastewater, sludge is mainly composed of hydrous metal compounds, such as metal hydroxides, rather than pure metal ions. Water treatment steps preceding settling are designed to promote precipitation, so that separation of metals can occur: pH adjustment reduces solubility of metals that form complexes with hydrogen, thus initiating the formation of precipitates, while oxidation changes the ionic form of the metal, reducing solubility further and increasing the extent of precipitation. In addition, pH levels must be adjusted to meet EPA discharge limits. Mixing (also referred to as agitation) is required to disperse the pH-adjusting chemicals in the wastewater, and may be necessary to contact the oxidant with the metal as well.

Coagulation and flocculation processes aid in the precipitation and settlement of metals. A coagulant is a chemical that suppresses a particle’s electric charge so that it will aggregate with other particles, forming agglomerations of solid metals large and heavy enough to settle out.4 Such agglomerations are sometimes called flocculations or, simply, “floes.” Flocculation generally refers to the process of binding together large numbers of suspended or coagulated solids. Floceulants are molecules that have many atoms and become highly ionized when dissolved, so that each flocculant molecule has many charged “sites” available to attract suspended or coagulated solids, and enmesh with other flocculant molecules. As the ionized sites bind with coagulated solids or other flocculant molecules, a “floe” builds up consisting of a large number of like particles in a process called “bridging.” Flocculation aids the process of settling by causing formation of larger, faster settling particles. The use of polymers as floceulants for removal of iron precipitates from water has been known since at least 1971, and for removal of iron, manganese, zinc, copper, lead, and chromium solid compounds since at least 1976.

[139]*139B. Description of the Patents at Issue

As noted, the ’497 and ’800 patents both relate to the treatment of waste water and are used in the PIT System, the device marketed by CST.

1. The’497 Patent

On January 21,1986, Mr. Stevenson, along with Richard S. Kanzleiter, Thomas G. Simo-netti, and Kenneth E. Ball, applied to the United States Patent and Trademark Office (the PTO) for the grant of a patent upon a “Method and Apparatus for Treatment of Acidic Water,” Ser. No. 820,955. The patent, as filed, was found by a PTO examiner to be obvious in light of Spinola, U.S. Patent No. 3,541,008 (Spinola), in view of Boester, U.S. Patent No. 3,210,053. After unsuccessfully attempting to distinguish his method from prior art, Mr. Stevenson abandoned the application and filed a continuation application with a preliminary amendment to the claim. The PTO continued the application, which was refiled on August 7, 1987, and then granted the continued application on June 7, 1988, at Patent No. 4,749,497. Subsequently, the ’497 patent was assigned to CST by the named inventors, as recorded in the PTO on November 2,1987.

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