E. I. Du Pont De Nemours & Co. v. Glidden Co.

67 F.2d 392, 1933 U.S. App. LEXIS 4483
CourtCourt of Appeals for the Second Circuit
DecidedNovember 13, 1933
Docket449
StatusPublished
Cited by18 cases

This text of 67 F.2d 392 (E. I. Du Pont De Nemours & Co. v. Glidden Co.) is published on Counsel Stack Legal Research, covering Court of Appeals for the Second Circuit primary law. Counsel Stack provides free access to over 12 million legal documents including statutes, case law, regulations, and constitutions.

Bluebook
E. I. Du Pont De Nemours & Co. v. Glidden Co., 67 F.2d 392, 1933 U.S. App. LEXIS 4483 (2d Cir. 1933).

Opinion

L. HAND, Circuit Judge.

This is the usual equity suit for the infringement of a patent for a product; that is, for a lacquer made of nitro-cellulose with oils and resins, and for articles coated with it. Infringement is conceded, but the judge declared all the claims invalid. To an understanding of the case a brief statement is necessary, which may be supplemented by resort to the opinion below. De Nemours & Co. v. Glidden Co. (D. C.) 1 F. Supp. 1007. The base of the lacquer in question is nitrocellulose, a derivative of cotton, which when dissolved in proper diluents may be sprayed or brushed upon the object to be varnished, or made to adhere to its surface by dipping. As the solvents are evaporable, they disappear with exposure, leaving a coating upon the object which is hard, tough and adhesive, with a smooth glossy finish. The thickness of the coat obviously depends upon the solids left after the solvents have evaporated, principally the -nitro-cellulose. The greater the proportion of this to the solvents, the thicker the coat, and an initially thick coat is what is desired, else the operation must be more often repeated. On the other hand, the greater the proportion of nitro-cellulose in the solution, the more viscous it is, and the harder to spray or brush. The optimum is therefore that solution which will contain most nitro-cellulose and remain most fluid. There would have been no problem, if nitrocellulose were all of one quality, in respect of thickening the solution into which it is put. It is not. In some conditions of the substance a given proportion in a solution will thicken it beyond practicable limits; in others, the same proportion will leave it fluid enough for use. This quality is known as its “viscosity characteristic.” To achieve a thick coating and keep the solution fluid enough for use, it was essential to produce a nitro-cellulose of low “viscosity character *393 istie,” and undoubtedly the art would have welcomed such a lacquer before Flaherty’s time; indeed, it had tried to find one. It would thicken each covering and avoid several additional coats.

Various processes were known long before the invention by which viseosity of nitrocellulose could be reduced; the patent especially mentioned one of these of recent origin, Pitman. However, as the viscosity is reduced, though the lacquered objeet will be covered more thickly, the coating becomes brittle and will crack or chip. Oils and other softeners prevent this by making it tough; resins make it stick, though they counteract the action of the softeners, and even with softeners the viscosity must not be too far reduced. The art entirely understood the action of these components and had used them for long. The patent did not pretend to rely upon any of these discoveries, and could not. It gave a recipe for reducing viseosity, and for oils or resins, but laid no claim to it or any part of it. It claimed no more than that to produce an effective lacquer of thick coating quality, the viscosity characteristic of the nitro-cellulose must be below a critical limit fixed in the claims. It left the art to its own devices as to how to reduce the nitro-cellulose to the required viseosity, and how by the addition of oils and resins to make the coat tough and adhesive. The examples or recipes were merely illustrations of how the product could be made; they were not part of the invention and the defendant has not followed them; nor indeed does the plaintiff at the present time. They are present merely to conform to the statute.

There are various ways of reckoning viscosity; for convenience we shall adopt the simplest, which is a scale in seconds. The specifications declare that, by following the examples given, “a 25 to 4-0 %” nitro-cellulose “solution may be obtained having a viseosity below” a stated limit, “being practically the upper limit for any commercial, solution which is to be used for coating without thinning” (page 2, lines 25-31). This upper limit, by the scale used in the disclosure, involved in fact nitro-cellulose of different characteristics at the two extremes. The characteristic of the nitro-cellulose of a 25% solution measured by that standard is 4.6 seconds; that of a 40% solution is much lower, between .2 and .5 seconds, according to the amount of sodium acetate used to reducá it. Perhaps Flaherty intended by these words to fix a lower limit of viseosity, but the language is obscure, and his claims suggest nothing of the sort. Yet it is a natural way to read the language to suppose that the 40% solution was indeed a lower limit, in spite of the verbal inappositeness of the phrase. However that may be, he did indicate very clearly in his specifications that the viscosity should not be too low. Thus his first example was of lowering it so far as to be too low “even for most purposes,” and of building it back by the addition of higher viseosity nitro-cellulose, “to a suitable working point.” Clearly he presupposed that the art would understand what that point was, and that it should not make a lacquer too brittle to be corrected by softeners. The art certainly responded, for it had that knowledge and followed him without difficulty. In these circumstances it appears to us irrelevant that the claims contained no lower limit, as indeed they did not. So construed, is the patent valid?

Upon the appearance of the patented lacquer, under its trade-name, Viscolac, the art very generally followed suit, coming to rest for the most part with “half second” nitrocellulose. Flaherty’s work was done in 1920, shortly after the close of the Great War, and at a time when vast stocks of nitro-cellulose were on hand, and when the pressure for its disposal had increased, as well as for some use for the existing plants. This may account for the stimulus to get an effective lacquer of thick coverage, but it does not explain all the facts. The uses of such a laequer had existed long before, and when it appeared, it largely invaded the field of varnish and in many fields supplanted its use; there is- no reason to suppose that if it had been available earlier, it would not have done the same. Furthermore, the art had unquestionably been experimenting with low viscosity nitro-cellulose for a number of years before Flaherty began. In 1913, and thus before the war, Doerflinger, a competent chemist, who later went to the Perry Austen Company, began to work upon low viscosity lacquers. His nearest approach to anything within Flaherty’s limits was his formula 415. The technical evidence as to its viscosity, is obscure and baffling. Doerflingeris tests at the time were made by pipettes, and then in only two very thin solutions. The extent to which he reduced viseosity depends upon his testimony; at.least there is a dispute as to whether the basis of the experts’ experiments, i. e., the defendant’s bill of particulars, was the same as that testimony. Doerflinger during reduction neutralized tho agent, ammonia, by which he reduced viscos *394 ity. There is a dispute as to how far in the duplication of his experiments his moment of neutralization was observed. Upon it the viscosity depended. The evidence being in so much dispute, the severe standard of proof for anticipation was scarcely met in our judgment; but, quite aside from that, we think that the testimony of the art is enough to forbid the conclusion that, whatever viscosity Doerflinger got, he had produced a lacquer such as Viscolae. The Perry-Austen Company was a substantial producer; its wares were sold in quantity.

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Bluebook (online)
67 F.2d 392, 1933 U.S. App. LEXIS 4483, Counsel Stack Legal Research, https://law.counselstack.com/opinion/e-i-du-pont-de-nemours-co-v-glidden-co-ca2-1933.