Application of Robert M. Cole

326 F.2d 769, 51 C.C.P.A. 919
CourtCourt of Customs and Patent Appeals
DecidedJanuary 23, 1964
DocketPatent Appeal 7033
StatusPublished
Cited by15 cases

This text of 326 F.2d 769 (Application of Robert M. Cole) is published on Counsel Stack Legal Research, covering Court of Customs and Patent Appeals primary law. Counsel Stack provides free access to over 12 million legal documents including statutes, case law, regulations, and constitutions.

Bluebook
Application of Robert M. Cole, 326 F.2d 769, 51 C.C.P.A. 919 (ccpa 1964).

Opinion

SMITH, Judge;

The Board of Appeals affirmed the examiner’s rejection of claims in appellant’s application 1 for a patent on a method and composition in which a low volatility insecticide, such as a pyrethrin, is propelled into the air by the subliming action of a highly volatile solid, such as paradichlorobenzene, a common moth-proofing material.

Claims, 4, 7, 9 and 10, all the claims remaining in the application, were finally rejected as “unpatentable over” Electrolux British Patent in view of either Chuck U. S. Patent or Algard British Patent. The issue thus presented arises under 35 U.S.C. § 103 and requires for its resolution a determination of whether the differences between the prior art and the invention as claimed were such that the claimed subject matter as a whole would have been obvious to one of ordinary skill in the insecticide art at the time appellant’s invention was made.

Rejected claims 4, 7 and 10 are drawn to a solid insecticide. Claim 4 is representative of this group of claims and is as follows:

“4. A solid insecticide comprising in admixture a first ingredient comprising a 20% mixture of a pyrethrin and petroleum solvent and a second ingredient comprising crystalline para-di-chloro-benzene, the first ingredient comprising from .01% to .02% of the total.”

Claim 7 differs from claim 4 in specifying .5 gram of a 20% pyrethrum, 80% petroleum solvent mixture and paradichlorobenzene to make up 500 grams.

Claim 9 is a method claim as follows:

“9. The method of establishing and maintaining, in the atmosphere of an enclosed space, a concentration, effective against insects in flight, of a low volatility insecticide material selected from the class consisting of allethrin and pyrethrins, which method comprises forming a solid mass of a mixture consisting essentially of such material and a solid material selected from the class consisting of paradichlorobenzene, camphor and naphthalene, and ex *771 posing said mass to the atmosphere in said space.”

Claim 10 covers the “mixture of claim 9.”

Appellant has pointed out that the problem faced by the art in using pyrethrin type insecticides is that while they are extremely effective in “knocking down” flying insects, they have very low volatility. This has required their general use in inert solvents in spray guns, or in combination with inert fluid propellants of the halogenated hydrocarbon type to produce aerosols, as in the familiar aerosol insecticide bomb.

As appellant points out, aerosols are fugitive by nature, and the aerosol bomb does not provide an effective means of establishing and maintaining over a substantial period of time an effective concentration of the insecticide in the atmosphere, even in an enclosed space.

In his brief appellant states:

“The present invention involves the discovery that a mixture of a low volatility insecticide of the pyrethrin type with a subliming solid such as paradichlorobenzene will sublime as a mixture and establish in the atmosphere a concentration of vapors including both pyrethrins and the carrier material * * *.
“Such a combination is particularly effective in protecting clothing in a closet against moths. The paradichlorobenzene is effective against larvae and eggs, but ineffective against moths themselves; the pyrethrins in the air are effective against flying moths but ineffective against larvae and eggs * *

Appellant’s specification discloses certain limits to the amount of pyrethrins which can be completely vaporized by a given amount of 'the subliming solid used as the carrier material and points out that in using such amounts the concentration of pyrethrins established and maintained in the atmosphere is as great as the temporary concentration achieved by the use of aerosols.

The prior art relied on by the Patent Office is as follows:

Chuck 2,376,327 May 22, 1945

Algard (British) 440,536 Jan. 1, 1936

Electrolux (British) 639,937 July 12, 1950

Chuck discloses a composition for use in demothing a closet, or like confined space, which comprises cedar sawdust impregnated with a solution containing paradichlorobenzene and ethylene dichloride as the volatile ingredients for producing a vapor lethal to moths, moth eggs and larvae, and a pyrethrum extract for killing moths by contact. Glycerin and carbitol are added for lengthening the effective life of the composition by retarding vaporization of the paradichlorobenzene and ethylene dichloride.

The British patent to Algard discloses a liquid insecticide for killing insects such as moths and their larvae and eggs. The insecticide is a mixture containing 200 kg. paradichlorobenzene, 220 kg. Borneo naptha, 830 kg. trichloroethylene and 3 liters pyrethrum extract of 18 percent strength per 1,000 liters. The patent points out that the insecticide may be sprayed on an article or into a room to be protected, and that both the liquid and its vapor have a killing action, and further states that the insecticide “ * * * does not leave any stains on textiles, furs or other delicate materials.”

The British patent to Electrolux discloses combining a volatile, solid insecticidal carrier, such as paradichlorobenzene, with an insecticide, benzene hexachloride (Gammexane), having a low volatility, to form compositions in solid form for treating clothing in a closet to kill insects and their larvae and eggs. *772 The compositions are asserted to be an improvement over similar compositions containing DDT as the insecticide of low volatility. The patent points out that for treating clothing'the improved compositions may be effectively utilized in the spraying device of a vacuum cleaner arranged to operate as a blower to distribute the insecticidal composition in a closet. The quantity of benzene hexachloride is adjusted so that none of it remains as a residue in the spraying device after the carrier has vaporized. The preparation of a satisfactory composition is described in the patent. About 5 percent benzene hexachloride is dissolved in a melted carrier such as paradichlorobenzene. The mixture is allowed to cool and harden, and is then crushed or pulverized. The compositions are stated to be “harmless when applied to delicate objects, especially articles of clothing and the like.”

Appellant has directed attention to certain differences between his invention and the prior art. Thus, as to the Chuck patent, appellant urges in his brief:

“The important points to note in connection with Chuck are:
“1. His composition is a liquid, absorbed in sawdust to be sure, but a liquid nevertheless. And he teaches that the vaporization of paradichlorobenzene and ethylene chloride is inhibited or reduced.
“2. Chuck also teaches that the pyrethrins do not vaporize, but rather remain on the objects to be protected, where they act as contact poisons.”

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Bluebook (online)
326 F.2d 769, 51 C.C.P.A. 919, Counsel Stack Legal Research, https://law.counselstack.com/opinion/application-of-robert-m-cole-ccpa-1964.