Application of Gerald S. Keim and William Donald Thompson

229 F.2d 466
CourtCourt of Customs and Patent Appeals
DecidedJanuary 20, 1956
DocketPatent Appeal 6155
StatusPublished
Cited by1 cases

This text of 229 F.2d 466 (Application of Gerald S. Keim and William Donald Thompson) is published on Counsel Stack Legal Research, covering Court of Customs and Patent Appeals primary law. Counsel Stack provides free access to over 12 million legal documents including statutes, case law, regulations, and constitutions.

Bluebook
Application of Gerald S. Keim and William Donald Thompson, 229 F.2d 466 (ccpa 1956).

Opinion

WORLEY, Judge.

This is an appeal from the decision of the Board of Appeals of the United States Patent Office affirming the rejection by the Primary Examiner of claims 37 to 42, inclusive, of appellants’ application for a patent on a process for sizing paper.

The claims have been treated as a unit throughout the consideration of the case in the Patent Office, and in the briefs before us, and it is evident that they must all stand or fall together. Consideration will therefore be confined to claim 37, which is illustrative. The claim reads:

“37. A process for sizing paper comprising forming a web of cellu *467 losic fibers, impregnating said web with an aqueous emulsion having in the dispersed phase a dimer of a higher organic ketene so that from 0.01 to 1.0%, based on the weight of the fibers, of said dimer is retained on the web, said ketene having at least 6 carbon atoms and having attached to the /'C" :r- -C:=--0 group only members of the class consisting of hydrogen and hydrocarbon radicals, and reacting said dimer with the cellulose fibers whereby sizing is imparted to the paper.”

The references relied on are: Nathansohn, 1,996,707, April 2, 1935; Nathansohn, 2,130,150, September 13, 1938; Deutsche (Gr. Br.), 522,204, June 12, 1940; Hanford et al., 2,284,896, June 2, 1942; Hentrich et al., 2,411,860, December 3, 1946; Broderick, 2,285,490, June 9, 1942; Downey, 2,627,477, February 3, 1953; Adams et al.— Organic Reactions, Yol. Ill, pages 127-132, 1946; Doggett et al., 2,482,578, September 20, 1949; Kantorowicz, 1,816,973, August 4, 1931; Manufacture of Pulp and Paper, Vol. 4, Sec. 4, page 23, 1928.

Appellants’ application here involved discloses a method of sizing paper which comprises forming a web of cellulosie fibers and impregnating it with an aqueous emulsion having in the dispersed phase a dimer of a higher organic ketene in such a manner that from 0.01 to 1.0 per cent, based on the weight of the fibers, is retained on the web. The dimer is then reacted with the paper to impart sizing to it. The application states that, instead of an aqueous emulsion, a solution of the ketene in an organic solvent may be used, although it is indicated that the aqueous dispersion is preferable.

The patent to Downey, No. 2,627,477, was granted February 3, 1953, on an application filed on the same day as appellants’ application here involved. It was stated by the Patent Office tribunals that appellants’ said application is presumed to be owned by the assignee of the Downey et al. patent and, since this statement has not been controverted, it will be accepted as correct. The patent discloses the preparation of an aqueous emulsion of ketene dimers of the type recited in the appealed claims and refers to the appellants’ present application as disclosing that paper may be sized by treatment with such a dimer. No other specific use for the aqueous emulsion is given in the patent, the claims of which are drawn to the emulsion without limitation as to use.

The patent to Hentrich et al. relates to water-repellent textiles, fibers, and the like. Paper is one of the materials casually mentioned, but the specific examples relate to satin and wool. The treatment disclosed comprises the application to the fibers of a solution of a higher molecular ketene in an organic solvent and it is conceded in appellants’ brief that the ketenes referred to are considered to be dimers. The concentration of the solution used in the patent is said to be from 0.5 to 8 per cent, the ordinary range being from 1 to 3 per cent. In the applicants’ brief on appeal to the Board of Appeals, it was stated that paper normally picks up about twice its own weight of an impregnating solution, so that Hentrich’s disclosure amounts to adding from 1 to 16 per cent of the dimer based on the weight of the fibers, with 2 to 6 per cent being recommended for ordinary operations. This statement by the applicant has not been questioned as to accuracy.

The British patent to Deutsche contains the same disclosure as Hentrich and is merely cumulative.

The patent to Hanford et al. discloses a process for rendering cloth or paper water-repellent by treatment with aqueous emulsions or solutions of various compounds. Among the compounds suggested are diketenes which, as the board stated, are to be distinguished from ketene dimers. No specific examples of the treatment of paper or of the proportions of materials to be used therefor are given.

The patents to Nathansohn were cited to show a recognition of the general equivalency of aqueous emulsions and *468 Solutions in the treatment of paper and textiles to render them water-repellent.

The Adams et al. publication was cited to show that ketenes dimerize when heated or allowed to stand at room temperature for a sufficient léngth of time.

The remainder of the references were cited to show the relationship between sizing and water-repellency. They were not discussed by the board and it is unnecessary to consider them in detail here, since the board agreed with the appellants that there is a distinct difference between sized paper and water-repellent paper. As pointed out by the appellants, paper is made water-repellent by completely covering the cellulosie fibers with a hydrophilic substance, such as wax, or by reacting the cellulosie molecules with chemicals which will change them to relatively hydrophilic compounds; whereas the purpose of sizing is to decrease the rate of penetration into the paper, without rendering it completely impervious.

It was the opinion of the examiner that, since sizing increases the resistance of paper to moisture, the difference between sized paper and water-repellent paper is merely one of degree. However, the references Cited do not indicate that that view has been taken by those skilled in the art, nor do they show that it has been customary to use the same materials for both purposes. On the contrary, the patent to Nathansohn, No. 1,996,707, states that it is not possible to make paper completely impermeable to water by the use of resin and alumina, which are conventional sizing materials. Únder those circumstances we do not consider that a disclosure in the prior art that a particular material could be used in rendering paper water-repellent would suggest the use of that material for sizing paper.

The appealed claims have been rejected on the patent to Hentrich.' As above noted, that patent is concerned primarily with the treatment of textiles and mentions paper only incidentally. The patent specification states'that the concentration of the impregnating solution may be varied to suit the materials used, but no specific figures are given for the treatment of paper, the examples given being limited to wool and satin. The patent, therefore, does not fairly disclose the use, in the treatment of paper, of the amounts of ketene dimers to which the appealed claims are limited.

Moreover, all Hentrich’s claims, as well as the disclosure of his specification, are directed to the production of water-repellent materials, and thus exclude sized paper, which does not repel water but merely absorbs it to a more limited extent than unsized paper does. There is nothing in the patent which would suggest the use of ketene dimers for sizing.

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229 F.2d 466, Counsel Stack Legal Research, https://law.counselstack.com/opinion/application-of-gerald-s-keim-and-william-donald-thompson-ccpa-1956.