Southern Electro-Chemical Co. v. E. I. Du Pont De Nemours & Co.

20 F.2d 97, 1927 U.S. App. LEXIS 2477
CourtCourt of Appeals for the Third Circuit
DecidedMarch 1, 1927
DocketNo. 3497
StatusPublished
Cited by3 cases

This text of 20 F.2d 97 (Southern Electro-Chemical Co. v. E. I. Du Pont De Nemours & Co.) is published on Counsel Stack Legal Research, covering Court of Appeals for the Third Circuit primary law. Counsel Stack provides free access to over 12 million legal documents including statutes, case law, regulations, and constitutions.

Bluebook
Southern Electro-Chemical Co. v. E. I. Du Pont De Nemours & Co., 20 F.2d 97, 1927 U.S. App. LEXIS 2477 (3d Cir. 1927).

Opinions

BUFFINGTON, Circuit Judge.

This patent concerns the denitration of sulphuric and the concentration of nitric acid by one of those continuous, straightway, unbroken unitary operations, to the urge for which so many industries have of late years responded. In that respect we note the general practice in the art here in question had separate, individual processes and apparatus for doing the two different things and making the two different products — one a low tower steam plant for denitrating sulphuric acid; and, second, a batch boiling plant for concentrating nitric acid. The patent here involved unified these two operations into one, substituted one apparatus for two, turned two overheads into one, and cut production cost virtually in half. Whether this patent is valid is the decisive question in the case, for, if valid, infringement is clear.

Confining present inquiry to the American art, which was no doubt well known to the patent authorities when called upon to grant the patent involved, we note that the state of the art in the United States, and we might add in Canada and England also, is evidenced by the methods used by the two great, leading companies, the Du Pont Company, the defendant, and the Curtis & Harvey Company, of Canada, which is a branch of the large parent company of that name in England. The practices of both companies in denitrating sulphuric acid and concentrating nitric acid were dual, nonunitary, and in that respect were substantially alike, and continued to be so used by them until they learned from the patentee his method. For denitrating the sulphuric acid in a mixture of nitric and sulphuric acid, Curtis & Harvey in their Canadian works used a countercurrent of steam in a tower of say 8 feet in height. They had seven such low towers, and the strength of the nitric acid produced was 59 to 60 per cent. The Du Pont Company had two denitrating low towers, not over 10 feet high, in which they also used a countercurrent of steam, and from them obtained from 50 to 60 per cent, strength. The concentration of nitric acid was also carried on by both companies .in an individual process and by an individual plant. This was known as the batch still method, wherein a batch of the acid mixture was put in a still and the nitric acid evaporated, after which the residuary sulphuric acid was removed, another batch put in and the process repeated. The nitric acid obtained, for example, by the Curtis & Harvey Company was so weak that, in order to highly concentrate it, they had to mix it with a strong sulphuric acid of about 94 per cent, and then subject it to the batch still process, by whieh it was concentrated to about 87 to 88 strength.

It will thus be seen that, in order to deni[98]*98trate sulphuric acid and to finally obtain highly concentrated nitric acid, these companies had to use two independent operations, two different plants, and provide two different kinds of heat, and neither of these different' methods or apparatus had any co-operating relation with the other. The cost of concentration by these successive, independent methods was about $22 to $24 per ton, and the life of the stills very short, due to high temperature. Though the use of these different tower heights, 8 and 10 feet, and of steam as a countercurrent, were factors familiar to these great companies, and equipped as they were also with scientific staffs of advanced thought, and with ample financial resources at their call, no departure from or variation in, or improvement of, these familiar agencies occurred to either of them. Such being the stand-still condition of the art in America, and for that matter everywhere, two men, Dr. Ragnar Sohlman, of Sweden, and Walter Atkinson Wilson, of Great Britain, attempted its improvement. They conceived the idea, and their disclosure was evidenced by patents here and abroad, of integrating the two separate denitrating and concentrating processes into one. This they proposed to do by departing from the. old dual art in' three particulars: First, for the short tower of the old art they substituted a long one; second, instead of using external heat around a batch still, they used it around their high tower; and, third, they gave up the steam of the old method for a countercurrent, and replaced it by a current of hot air “or any other gas.”

That the use of gas, and consequently the nonuse of steam, for their countercurrent, by Sohlman and Wilson, was the essence, or, as they term it, “the main feature,” of their proposed improvement is shown both by their specification and claims. Taking their United States patent, No. 1,009,196, applied for April 16, 1909, and granted November -21, 1911, we find their specification stating: “The process consists, chiefly, in having the acid or mixture of acids, or the like, to be treated, flow continuously down through a vertical conduit or column of acid-proof material filled with silicá or the like and heated externally, and leading a current of hot air or wny other gas in opposite direction through the said conduit or column. * * * The dis.tillation of the water or the nitric acid is in both cases facilitated by the hot air, or the like, supplied from the preheater and flowing upward through the column. This inner current of gas increases in a high degree the efficiency of the apparatus and forms the mam feature of the present invention.”

Upon this specification they received a patent containing two claims, the first of which has an element “supplying at the bottom of the closed chamber a continuous current of a heated vaporizing gas, which is cooled during its ascent among the subdivided streams, and exterially heating said chamber by a continuous- current of' hot gases, also decreasing in temperature from the bottom to the top of said chamber, to supply heat to the liquid during its descent,” etc.; and the second, “supplying a heated vaporizing gas into the bottom of the chamber, and heating the opposed currents of acid mixture and gas by heat conducted thereto from a current of hot gases decreasing in temperature from the bottom to the top of said chamber, the path of flow of the acid mixture being sufficiently long with respect to the temperatures of the gases at the bottom of the chamber to deliver mainly nitric acid vapor from the top of said chamber and dilute sulphuric acid at the bottom of the chamber.”

As bearing on the later discussion of the alleged anticipation by Sohlman and Wilson by this patent of the combined use of steam countercurrent and a tall tower, which is the method involved and in issue in this case, we here note that whatever changes or modification of their method might be made, or however seemingly slight those changes might prove to be, in the light of later events, it is certain that the patent neither disclosed or contemplated or claimed the use of steam as a countercurrent agency, and if the art had stopped where Sohlman and Wilson’s patent disclosure left it, steam as a countercurrent in a long tower would not have been taught by them, and would not have been known and utilized by the public.

About a year later, Pauling, who had works in Austria and was himself a practical man in the art, undertook to improve the art. Without discussing the laboratory experimental work leading up to it, all of which is proven in the record, we may say that the change Pauling made was so simple, and on the surface seemingly so small, that it is difficult at first sight, in view of the scientific staffs employed by these great companies, to understand why it was not done before, and, indeed, how it involved invention to do it.

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20 F.2d 97, 1927 U.S. App. LEXIS 2477, Counsel Stack Legal Research, https://law.counselstack.com/opinion/southern-electro-chemical-co-v-e-i-du-pont-de-nemours-co-ca3-1927.