NORDBYE, District Judge.
The Court heretofore had determined as the result of the first hearing that the patent was invalid primarily by reason of the teachings of one Niepce as reflected in his article published in London in the Photographic News on June 3, 1859. Reference also was made in the Court’s memorandum decision to the so-called Hunt article in the Philosophical Magazine and Journal of Science of July-December, 1840. The Court filed its memorandum decision on March 16,1962. Findings of fact and conclusions of law were filed on July 17, 1962. In view of the finding of patent invalidity, the Court did not discuss the question of infringement and the alleged file wrapper estoppel.
Plaintiff filed a motion for new trial pursuant to the provisions of Rules 59 and 52(b), Federal Rules of Civil Procedure. The motion was based upon alleged errors of the Court and upon the ground of newly discovered evidence. [981] After a hearing, the Court on November 2,1962, vacated its memorandum decision of March 16, 1962, and the findings of fact and conclusions of law and the judgment entered thereon, and granted plaintiff a new trial on the issue of the validity of the Miller patent. The new trial was heard on December 17 to 20, 1962. Both sides presented evidence, and the validity of the patent, therefore, is to be determined not only on the evidence before this Court at the first hearing from February 27,1961, to March 3,1961, but also on the evidence produced at the hearing from December 17 to 20, 1962.
The newly discovered evidence pertains to the discovery by the plaintiff of the original article in French presented by Niepce to the French Academy on May 23, 1849. The account published in the Photographic News purported to be an English translation thereof. The principle difference in the original French text and that which appears in the English translation is to be found wherein Niepce specifically states in the French text that a greasy ink image could be produced on sensitive paper when exposed to his method of heating, although aqueous or water-based ink would not produce copies. Plaintiff contends that the original French text confirms its position that it is the difference in the chemical constituents of the ink and not its absorptivity that Niepce noted when he discussed his success with printer’s ink and his lack of success in using ordinary ink.
When the patent validity question was first considered by this Court, the position taken by the parties was substantially the same as that which is presented by the new evidence. However, the experiments' made according to the teaching of Niepce have been greatly extended and broadened. Moreover, the evidence as to the difference as to the absorptivity of heat by graphic images as compared to the paper on which the images appear when heated to 100° C. has been convincingly established. In other words, the entire evidence impels a finding that there can be no heat pattern from any radiation produced at the temperature of boiling water. All of Niepce’s experiments were made with a metal plate heated to 100° C., except that he does state that
“Paper prepared with very dilute nitric acid (1 percent.), or with a solution of 45 grains of cyanide of potassium to the ounce of water, is sufficiently sensitive to yield thermographic images, but only at a much higher temperature than 212° Fahr.”
He states also, in referring to the images he produced, that “if it be not sufficiently distinct, it may be forced out by exposing the sheet of paper to the radiant heat from a fire.” But there is nothing in Niepce’s teachings which would indicate that in the use of any of these chemicals ■ — nitrate and cyanide of potassium- — -in making heat-sensitive paper, he was aware that there would be any heat differential pattern created by radiant energy whereby the images on the original would absorb the increased radiation and conduct heat to the sensitive sheet and thus produce a copy.
The French text does lend weight to plaintiff’s position that the reproduction of the printed page as produced by Niepce was due to the chemicals in the ink rather than by reason of any heat transfer. But the ultimate question before the Court is' whether Niepce disclosed the placing of a graphic original in close contact with a heat-sensitive paper and then by radiant energy created a heat differential pattern whereby the characters on the paper would absorb the radiation and conduct that heat to his heat-sensitive paper and produce a copy. Or, stating it another way, did Niepce merely produce a-copying of the graphic original on to the heat-sensitive paper by the application of heat and produce a chemical or a mere transferring by conduction of the graphic original on to the heat-sensitive paper?
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NORDBYE, District Judge.
The Court heretofore had determined as the result of the first hearing that the patent was invalid primarily by reason of the teachings of one Niepce as reflected in his article published in London in the Photographic News on June 3, 1859. Reference also was made in the Court’s memorandum decision to the so-called Hunt article in the Philosophical Magazine and Journal of Science of July-December, 1840. The Court filed its memorandum decision on March 16,1962. Findings of fact and conclusions of law were filed on July 17, 1962. In view of the finding of patent invalidity, the Court did not discuss the question of infringement and the alleged file wrapper estoppel.
Plaintiff filed a motion for new trial pursuant to the provisions of Rules 59 and 52(b), Federal Rules of Civil Procedure. The motion was based upon alleged errors of the Court and upon the ground of newly discovered evidence. [981] After a hearing, the Court on November 2,1962, vacated its memorandum decision of March 16, 1962, and the findings of fact and conclusions of law and the judgment entered thereon, and granted plaintiff a new trial on the issue of the validity of the Miller patent. The new trial was heard on December 17 to 20, 1962. Both sides presented evidence, and the validity of the patent, therefore, is to be determined not only on the evidence before this Court at the first hearing from February 27,1961, to March 3,1961, but also on the evidence produced at the hearing from December 17 to 20, 1962.
The newly discovered evidence pertains to the discovery by the plaintiff of the original article in French presented by Niepce to the French Academy on May 23, 1849. The account published in the Photographic News purported to be an English translation thereof. The principle difference in the original French text and that which appears in the English translation is to be found wherein Niepce specifically states in the French text that a greasy ink image could be produced on sensitive paper when exposed to his method of heating, although aqueous or water-based ink would not produce copies. Plaintiff contends that the original French text confirms its position that it is the difference in the chemical constituents of the ink and not its absorptivity that Niepce noted when he discussed his success with printer’s ink and his lack of success in using ordinary ink.
When the patent validity question was first considered by this Court, the position taken by the parties was substantially the same as that which is presented by the new evidence. However, the experiments' made according to the teaching of Niepce have been greatly extended and broadened. Moreover, the evidence as to the difference as to the absorptivity of heat by graphic images as compared to the paper on which the images appear when heated to 100° C. has been convincingly established. In other words, the entire evidence impels a finding that there can be no heat pattern from any radiation produced at the temperature of boiling water. All of Niepce’s experiments were made with a metal plate heated to 100° C., except that he does state that
“Paper prepared with very dilute nitric acid (1 percent.), or with a solution of 45 grains of cyanide of potassium to the ounce of water, is sufficiently sensitive to yield thermographic images, but only at a much higher temperature than 212° Fahr.”
He states also, in referring to the images he produced, that “if it be not sufficiently distinct, it may be forced out by exposing the sheet of paper to the radiant heat from a fire.” But there is nothing in Niepce’s teachings which would indicate that in the use of any of these chemicals ■ — nitrate and cyanide of potassium- — -in making heat-sensitive paper, he was aware that there would be any heat differential pattern created by radiant energy whereby the images on the original would absorb the increased radiation and conduct heat to the sensitive sheet and thus produce a copy.
The French text does lend weight to plaintiff’s position that the reproduction of the printed page as produced by Niepce was due to the chemicals in the ink rather than by reason of any heat transfer. But the ultimate question before the Court is' whether Niepce disclosed the placing of a graphic original in close contact with a heat-sensitive paper and then by radiant energy created a heat differential pattern whereby the characters on the paper would absorb the radiation and conduct that heat to his heat-sensitive paper and produce a copy. Or, stating it another way, did Niepce merely produce a-copying of the graphic original on to the heat-sensitive paper by the application of heat and produce a chemical or a mere transferring by conduction of the graphic original on to the heat-sensitive paper?
Admittedly, the reproduction of the graphic original on to Niepce’s conventional heat-sensitive paper when these papers are placed in close contact in a book without any heat, as disclosed by [982] plaintiff’s new evidence, must be a process of chemical action. It cannot be successfully urged that in exposing this heat-sensitive paper with the graphic images produced under such circumstances “to the radiant heat from a fire” in order to make the image more distinct, this exposure to heat would be an illustration of the teachings of Miller in the use of radiant energy. A similar experiment with Thermofax paper and a graphic image placed in a book produced no reproduction. Likewise, when a graphic ink image is placed between two glass slides and heated to 100° C., and then the graphic image is removed and Niepce’s heat-sensitive paper is placed between the same glass slides and reheated, with a reproduction of the image on the heat-sensitive paper, the only explanation of this phenomena is that it represents a chemical process. And when a word is written in pencil on an ordinary sheet of paper with ruled lines and then this sheet is placed in close contact with Niepce’s paper coated with silver nitrate and gold chloride and placed on a plate and subjected to the heat of boiling water, the ruled lines appear, but the wx-iting with the pencil does not appear, the only explanation must be that a chemical process in obtaining the transfer was involved. When this experiment was produced with Thermofax paper and the Miller method, the pencil writing was reproduced, but not the ruled lines. It seems clear, therefore, that the inability of Niepce to reproduce carbon images was due to the fact that the black carbon inscriptions did not have the chemical ingredients to be reproduced on his sensitive paper at 100° C. And, moreover, the undeniable fact is from the evidence that at that temperature (100° C.) the absorptivity of the paper and the black carbon is substantially the same so that no heat differential pattern could be created. The Court over-simplified Miller’s teachings in its original memorandum when it stated that Niepce accomplished the same results as Miller when he placed a heat-sensitive sheet in contact with a graphic original, and upon exposing this couplet to the heat produced from a hot plate in contact with boiling water, a positive copy of the graphic original was obtained. The Court correctly stated Niepce’s process, but failed to recognize that, although this early experimenter was aware that heat was essential to trigger the x-eproduction of a graphic image on heat-sensitive paper, he did not create a heat differential as between the graphic image and the paper on which the images, appeared, and thus produce a reproduction of the images on heat-sensitive-paper. And when Niepce stated that, “calorific radiation” had much to do with it, “but the material vapours emanating-from the heated objects doubtless play their part,” this statement was not used in connection with any phenomena such as Miller taught in using radiant enex*gy to create a heat differential pattern in-the original graphic image. Rather,. Niepce assumed that the heat and: “vapours” he noted were present for the: purpose of stimulating and effecting the-chemical processes which he achieved. He did not conceive that selective heating had to be effected. This conclusion must: be sound in view of the weight of the; evidence that there is no substantial difference in the absorptivity of papex- and carbon black when heated to the: temperature of boiling water. Obviously, a uniform temperature absorbed by the-graphic image and the paper on which it. appears will not create a differential heat, pattern so as to form a heat image on-heat-sensitive paper. In fact, the evidence is convincing that with a temperature as high as 200° C., the radiation produced is so slight that it is-absorbed by the white paper and relatively none of it reaches the carbon black., The evident reason, therefore, whyNiep-ce could produce images from, printer’s ink and could not from cax-bonmarkings was due to the fact that he-was dealing with chemical processes and: not heat differentials as between the-paper and the images thex*eon. And it: is no answer to suggest the Niepce must have been dealing with old printed pages-in performing his experiments and there[983] fore that the printed pages with which he dealt had lost much of their chemical ingredients, and hence one should conclude that he was not creating some chemical phenomena. The experiments made in Court as to the ability of Niepce’s method to reproduce ink images, and the failure when the chemical constituents of the ink were eliminated, would indicate that in his experiments Niepce was dealing with ink printing which had sufficient fats and oils so as to enable him by chemical processes to produce images on his heat-sensitive paper.
Although a reading of Niepce’s paper may indicate in some instances that he knew that designs of dark parts were more sensitive by their reproduction by heat than the lighter parts of the paper on which the image appears, his understanding of their reproduction was based upon their chemical consistency rather than their heat absorptivity. The anomaly of cotton, colored blue with indigo with white spaces, producing a positive image, while Prussian blue on the same or similar material would be negative with the the white parts giving the image, and which puzzled Niepce, can •only be explained by some chemical reaction, if it can be explained at all. And when he stated that “the intimate nature of the colouring matter or of the ink” influenced his ability to reproduce the image in that from one he obtained a positive and from the other a negative impression, it must be concluded that he ■was speaking of a chemical phenomena.
Defendant readily concedes that in •some of his experiments Niepce was ■dealing with chemical processes. But it •contends that graphic images can be produced by heat differentials according to 'Niepce’s methods, and it sought to demonstrate its position by placing a cover glass about the size of a ten cent piece over part of an ink graphic image of •triangular shape, and with Niepce’s con•ventional heat-sensitive paper of gold ■ chloride and silver nitrate in close contact subjected to 100° G. for some 60 minutes, it was able to produce the image including -.that partly covered by the glass piece, although that portion of the image appeared with some imperfections. It is defendant’s contention that the arrangement of this assembly removed all possibility of any chemical interaction between the chemical of the ink image covered by the glass cover piece and the heat-sensitive paper. Plaintiff’s testimony was to the effect that its expert was unable to obtain any reproduction of the portion of the image under the glass in its attempt to perform the same experiment. Its position is that the reproduction of the image under the small cover glass must have been produced in defendant’s experiment by conduction due to the arrangement of the assembly. Moreover, plaintiff contends that the amount of radiation passing through the small glass cover piece would be too insignificant to create a reproduction. And as to the relevancy of this experiment in attempting to interpret the teachings of Niepce, attention may be directed to the portion of his article wherein he stated that
“With the paper prepared with the salts of both silver and gold, and using the plate heated to the boiling point of water, the large letters of the print are copied at a distance of several millimetres; but the effect does not take place if there be interposed a continuous film of mica, metal, or even of rice paper, however thin it be.”
Defendant proffered the results of certain experiments with heat-sensitive paper made with a nitric acid solution and that made with a solution of cyanide of potassium. As before indicated, Niepce stated in his article that heat-sensitive paper with these solutions would “yield thermographic images, but only at a much higher temperature than 212 degrees Fahr.” Niepce did not disclose the results of his experiments with these types of heat-sensitive papers. However, at this hearing, defendant prepared heat-sensitive paper with these solutions and increased the heat source from 100° C. to about 460° C. An original sheet with an ink image was placed in close contact [984] with the heat-sensitive sheet, with a Mylar film covering one-half of the image, and after an exposure of this assembly for about one minute some two inches from the heat source, a charred sensitive sheet resulted with a darkened image visible thereon, but less distinct where the Mylar film covering had been placed. Defendant contends that in that the Mylar film being completely impervious to any chemical transmission of the darkened images to the heat-sensitive paper, this result sustains its position that Niepce’s teachings included the production of a heat differential pattern by the conversion of radiant energy into heat which was absorbed by the darkened images and thus produced on the heat-sensitive paper. In one of the experiments at 460° C., a carbon pencil mark was faintly produced on a charred HNO3 sensitive sheet.
It does not seem necessary to recount in detail the results attained by plaintiff’s experts in utilizing cyanide and nitric acid heat-sensitive paper. Suffice it to say that, according to the evidence, plaintiff’s experiments failed to produce any reproduction with cyanide or nitric acid heat-sensitive paper when heated at various degrees of heat from 300° C. to 1,000° C., except at the higher heat there were particles of charcoal which were picked or rubbed off on to the sensitive sheet. Whatever phenomena may have caused the darkened graphic image on the charred nitric or cyanide heat-sensitive papers when subjected to a heat of 460° C. in defendant’s experiments, such charred reproductions are a far cry from the commercial reproduction of a printed page by a heat temperature differential on a heat-sensitive sheet as taught by Miller.
Benjamin Franklin recognized that dark clothes would absorb the sun’s rays more readily than white ones, but if Niepce was assuming to carry out that well-known phenomena, he demonstrated quite the reverse in that graphic images of white ink when heated to 100° C., would be reproduced when placed on a black background, and when a black ink image was volatilized so as to eliminate or reduce the ink ingredients, no reproduction was obtained at 100° C. And the only time when a darkened carbon image, which should be most susceptible of absorbing heat created by radiant energy, was reproduced by anything that Niepce taught, it was by use of a cyanide heat-sensitive paper heated to some 460° C., and then a rather sorry exposition of an alleged heat differential pattern resulted.
It seems evident after the exhaustive experiments made by qualified scientists on each side that that which Niepce sought to teach, and did teach, was the reproduction of graphic images of printed characters, and also to copy coins, cameos, fabrics, feathers and engravings on to heat-sensitive sheets primarily by chemical processes or conduction induced by heat. And any attempt to construe his teachings as envisaging the creation of a heat differential pattern as between graphic images and the paper on which they appeared so as to reproduce the images on heat-sensitive paper by reason of the images absorbing the heat created by radiant energy, is to read in his literature this phenomena in light of the teachings of Miller. And one must not overlook the fact that there is unanimity among all the experts who testified that heat which merely creates a chemical phenomena by the transfer of graphic images on to a heat-sensitive sheet bears no relation to the phenomena of creating a heat differential pattern whereby radiant energy produces heat which is absorbed by the graphic images and thereby transferred to a heat-sensitive sheet. In Miller we are considering the intensity of radiation which is some 2,500 times greater than the intensity created at 100° C. And clearly, Niepce never conceived that not only must there be radiant energy converted into heat, but that it also must be applied briefly and with high intensity. The type, duration or intensity of radiant energy as taught by Miller is not to be found in Niepce.
The statement made by one of the expert witnesses of the defendant at the [985] rehearing may be noted. In referring to Niepce’s article, he stated:
“This whole article is vague as it is written. Today it wouldn’t be accepted for publication. There aren’t enough details in many places. One has to fill in as best as one can from one’s scientific experience.” (Tr., p. 237). .
This statement is particularly pertinent when one assumes to glean from Niepce’s teachings the advance in the art made by Miller. Not only is Niepce’s article vague in many particulars, but it is puzzling even today to learned scientific men. And of course the undeniable fact is that Niepce’s article awakened no progress in the art for over one hundred years.
On this record, the Court cannot find with any assurance that in Niepce’s teachings it would be evident to one skilled in the art that by the application of intense radiant energy to a couplet of a graphic image page and a heat-sensitive sheet there would be produced speedily and effectively a heat differential pattern so as to reproduce a graphic original on to the heat-sensitive sheet. The evidence produced by the plaintiff at the retrial has fulfilled the showing made by the affidavits filed in support thereof. And upon further consideration of Niepce’s article and Hunt’s teachings,