Liquid Chemical Corp. v. Department of Health Services

227 Cal. App. 3d 1682, 279 Cal. Rptr. 103, 1991 Cal. App. LEXIS 84
CourtCalifornia Court of Appeal
DecidedJanuary 30, 1991
DocketF012645
StatusPublished
Cited by5 cases

This text of 227 Cal. App. 3d 1682 (Liquid Chemical Corp. v. Department of Health Services) is published on Counsel Stack Legal Research, covering California Court of Appeal primary law. Counsel Stack provides free access to over 12 million legal documents including statutes, case law, regulations, and constitutions.

Bluebook
Liquid Chemical Corp. v. Department of Health Services, 227 Cal. App. 3d 1682, 279 Cal. Rptr. 103, 1991 Cal. App. LEXIS 84 (Cal. Ct. App. 1991).

Opinion

Opinion

VARTABEDIAN, J.

We are called upon to determine the propriety of an enforcement action taken by the State of California acting through its Department of Health Services (DHS) under provisions of the California Hazardous Waste Control Act (HWCA) which took effect on January 1, 1987. Specifically, appellants, Liquid Chemical Corporation (LCC) and Donald Garrett, claim DHS lacked jurisdiction because rules and regulations applied against them were not lawfully adopted and/or appellants’ materials in question are not “hazardous waste.” Garrett additionally contends that he should not be personally liable. We reject each of these claims and affirm the superior court judgment.

*1687 Factual and Procedural Background

LCC’s facility is located in an industrial park a few miles south of Han-ford, California. The site contains six surface impoundments (storage ponds), digesters, a granulator, office space, drum storage, storage bins and unused land. LCC is in the business of manufacturing liquid and granular micronutrient 1 fertilizer.

Garrett’s educational background includes a doctorate in chemical engineering. He has been president of LCC since 1980 when he bought out the corporate shares held by other officers. Although his testimony was rather ambiguous, it appears that the corporation currently has only three shareholders.

Before 1985, steel mill flue dust was the major raw material used by LCC. That dust results from a process wherein scrap iron is melted in furnaces. It resolidifies into small particles that are captured in an emission control device. LCC manufactured zinc sulfate from the steel mill flue dust by putting it into sulfuric acid. The leftover liquid from the manufacturing process was sent to the storage ponds located at the site.

Steel mill flue dust was designated a hazardous waste in 1985 by the federal Environmental Protection Agency (EPA) and given the reference code number KOI6. Each of LCC’s 6 ponds contains KOI6 slurry. 2 The slurry is about 10 percent zinc, 1.7 percent lead, .10 percent cadmium, and .10 to .20 percent copper by dry weight. A total estimated 30,000 tons of material are contained in the 6 ponds.

Since 1985, LCC has used sal skimmings, galvanizer’s ash, ball mill fines, filter cake, zinc hydroxide, and zinc baghouse flue dust as its raw materials. Most of these result from practices in the galvanizing industry.

Galvanizing is a process by which metal, usually steel or iron, is plated or coated with zinc to protect the base metal from rust or corrosion when exposed to air or water. The “hot dip” method is the most popular method of galvanizing used in the United States. Molten zinc, with a temperature of about 850 degrees Fahrenheit, is contained in a kettle. Floating on top of the molten zinc is a flux solution, usually ammonium chloride or *1688 zinc ammonium chloride. The base metal is put through the flux, which cleans and prepares the surface of the metal to accept the zinc coating.

After a number of pieces of material are put through the flux and the zinc in that fashion, some of the zinc becomes mixed in with the flux. The flux becomes sluggish because of picking up portions of the zinc, dirt, or other impurities from the metal, and because the ammonium chloride changes its chemical composition when it comes into contact with the air. The flux is then skimmed off, resulting in what is referred to in the trade as sal skimmings.

Galvanizer’s ash, also called zinc ash, zinc oxide or zinc top dross, is another byproduct of the steel galvanizing process. When the kettle that contains the flux and the zinc is skimmed, it causes oxidation and a certain amount of ash generates on the kettle.

Galvanizer’s ash is sometimes crushed to recover the metallic zinc content. After the metallic zinc is removed, oxidic zinc is left. This is called ball mill fines or ball mill ash.

In the hot dip method of galvanizing, before the metal is placed into the zinc, it passes through a “pickle liquor” of sulfuric acid. Zinc hydroxide is produced when the metal content of that solution is removed.

When zinc is applied by electroplating, the base metal is placed into a zinc acid solution. Filter cake is produced from the rinse waters through the electroplating system. It is approximately 8 to 15 percent zinc.

Zinc baghouse dust results from the melting of scrap metal. The fumes are primarily zinc oxide. They are collected in a baghouse. 3

The materials used to manufacture the fertilizer all contain some lead as well as the zinc. The ball mill fines contain the most zinc.

LCC puts the sal skimmings or other raw materials into sulfuric acid to dissolve the various zinc raw materials coming in and converts them to zinc sulfate. “Converting” is a chemical reaction.

The diluted zinc from the ball mill fines is put into the storage ponds.

*1689 In 1987, a corrective action order and complaint for penalty was issued by the DHS. The second amended complaint charged LCC and Garrett with 10 violations of the Health and Safety Code or of the California Administrative Code, 4 specifically:

(1) Violations of Health and Safety Code sections 25154 and 25200.5, title 22, California Administrative Code, section 66389, and LCC’s interim status document section 1, paragraph 4, and section 2, paragraphs (a)(1) and (b), by storing, treating and disposing of hazardous waste without a permit and without the payment of appropriate fees.
(2) Violations of title 22, California Administrative Code, section 66515, importing hazardous waste from Canada and Mexico without notifying the DHS and without filing the required manifests.
(3) Violation of title 22, California Administrative Code, section 67166, and section 7, paragraphs 2 and 5 of LCC’s interim status document, by receiving hazardous waste from within California without notifying the DHS and without filing the required manifests.
(4) Violation of title 22, California Administrative Code, section 67003, by failing to provide for financial assurance for closure of the facility.
(5) Violation of title 22, California Administrative Code, section 67027, by failing to obtain and maintain liability insurance.
(6) Violation of title 22, California Administrative Code, section 67015, by failing to provide financial assurance for postclosure care.
(7) Violation of title 22, California Administrative Code, section 67212, subdivision (a), by failing to submit an adequate closure plan.
(8) Violation of title 22, California Administrative Code, section 67310, by failing to maintain two feet of freeboard in their surface impoundments.

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Bluebook (online)
227 Cal. App. 3d 1682, 279 Cal. Rptr. 103, 1991 Cal. App. LEXIS 84, Counsel Stack Legal Research, https://law.counselstack.com/opinion/liquid-chemical-corp-v-department-of-health-services-calctapp-1991.