Electrical Accumulator Co. v. Brush Electric Co.

52 F. 130, 2 C.C.A. 682, 1892 U.S. App. LEXIS 1385
CourtCourt of Appeals for the Second Circuit
DecidedOctober 4, 1892
StatusPublished
Cited by22 cases

This text of 52 F. 130 (Electrical Accumulator Co. v. Brush Electric Co.) is published on Counsel Stack Legal Research, covering Court of Appeals for the Second Circuit primary law. Counsel Stack provides free access to over 12 million legal documents including statutes, case law, regulations, and constitutions.

Bluebook
Electrical Accumulator Co. v. Brush Electric Co., 52 F. 130, 2 C.C.A. 682, 1892 U.S. App. LEXIS 1385 (2d Cir. 1892).

Opinion

Shipman, Circuit Judge.

This is an appeal from a decree of the circuit court for the southern district of New York, which enjoined the defendants against the infringement of the 7th and 14th claims of letters patent No. 266,090, dated October 17,1882, and of the 1st, 2d, 3d, 6th, 7th, and 12th claims of letters patent No. 337,299, dated March 2,1886, each of said patents having been granted to Charles F. Brush for improvements in secondary batteries for the current storing of electrical energy. The applications were filed as follows: that of No. 266,090 on June 9, 1881, and that of No. 337,299 on June 13, 1881.

The subject-matter of this litigation has been three times examined by Judge Coxe, in the cases of the present defendant against the Julien Electric Company, (38 Fed. Rep. 126,) of the present complainant against the Julien Electric Company, (41 Fed. Rep. 679,) and in this suit, (47 Fed. Rep. 48.) This repeated scrutiny has caused some of the questions which were presented in the pleadings to disappear from the case, while the vigor of other defenses, which have been successively supported and resisted, has become impaired. The questions which still remain for investigation are important, and, mainly by reason of the numerous patents which Mr. Brush has taken, are entangled; but the three opinions which have been written have freed the subject from much of its perplexity.

Patent No. 337,299 is the most important, and will be first considered. It solely relates to secondary batteries. A secondary battery was well defined by Judge Coxe to be “a battery which has no original power of developing a current of electricity, and is active only when rendered so by sending a current, elsewhere generated, through it.” Sir William, [132]*132Thomson, in his deposition in the first Julien Case, had stated the distinction between a primary and a secondary battery, as follows: “A secondary battery is a battery which is active only when rendered so by sending a current through it from an independent source of electric energy. A primary battery is one which is active in virtue of the materials of which it is made.” Electricity is chemically generated by virtue of these materials. The electrodes are unlike and inherently differ from each other electro-motively. The positive plate is dissolved in the battery fluid in which it is placed, and which is ordinarily dilute sulphuric acid. “The other electrode collects the electric energy from the liquid, and by this chemical union a current of electricity is developed.” The two electrodes of a purely secondary battery are of the same kind, are not separated electro-motively, and are insoluble in the battery fluid, but, “by subjecting these elements to the action of an electric current, the two elements are differentiated and rendered electro-positive and electro-negative with respect to each other, depending entirely on which is connected with the positive pole of the charging generator and which with the negative pole thereof.” The electrodes absorb either the hydrogen or oxygen which is set free from the liquid by the charging current, which in popular, though not in scientific, language, is called absorbing electricity; hence the significance of the name “ storage battery,” which suggests the idea of continuance or duration of use. The capacity of a primary battery to give a current is limited; it is soon exhausted; “ while in the secondary battery the amount of current which may be obtained depends entirely upon the resistance of the conducting wires discharging it,” and the battery may be charged and discharged for an indefinite number of times. The commercial importance of a secondary battery is easily recognized from this statement of its points of unlikeness to a primary battery.

Prior to the invention of the Brush and the Faure batteries, the only secondary battery in use was that of Plante, which was invented about the year 1860. The following statement of the chemical effect of the successive charges of the electric current upon the two plain plates of rolled or pressed lead, of which this battery was composed, is condensed from the more elaborate statement in the appellee’s printed argument: The plates having been immersed in an electrolyte of dilute sulphuric acid, and having been respectively connected to the two poles of any suitable source of electricity, by means of which a current was passed through the plates, oxygen was developed on one plate and hydrogen on the other. The hydrogen passed off in bubbles; leaving its lead plate practically unaffected, but the oxygen combined chemically with the lead of the other plate until it had formed a film or skin of peroxide of lead, of a finely-divided, granular character, like rust. The skin of peroxide, operating to protect the underlying lead, soon stopped the action of the oxygen on the lead. A small current or discharge was produced , but too small to be of value. Plante ascertained that there must be corresponding!}' thick films on each plate. He therefore reversed the direction of his current, developed oxygen on the hydrogen plate and [133]*133hydrogen on the oxygen plate, which took away the oxygen from the oxide film and left the surface granular or spongy metallic lead. These reversed charges were repeated for days and sometimes for weeks. The result was to disintegrate, through the action of electricity, the surface of the plain lead plates, and to form spongy layers of lead thereon. This granular layer is what is called the active material of the battery; that is, material which becomes practically and actively capable of receiving and discharging electricity by the passage of an electric current. The core of the original plate mechanically supported the active material and conducted the current through it. This operation of the breaking up of the surface of solid lead plates so as to create porous coatings, in other words, of the “ formation ” of the active material of a battery by electrical disintegration, was the distinguishing feature of the Plante secondary battery. It occupied a long and therefore expensive amount of time, and was incumbered by other mechanical difficulties, one of which was the thinness of the layers, and another, the tendency of the layer to peel off from the plate. These minor defects were partially avoided by increasing the number and diminishing the surface of the plain plates.

The improvement described in No. 337,299 was confessedly an improvement upon the Plante battery and upon no other, and, in the language of the specification, consisted “broadly in a secondary battery plate or element having active or absorptive material primarily and mechanically applied thereto or combined therewith, as contradistinguished from a plate or element having the active material produced by the disintegrating action of electricity, as in the well-known Plante process.” The mechanical application of a layer of lead oxide to each one of two lead plates, before the plates are placed in the battery fluid,—these coatings being at once active material, and ready for the charging current when immersed in the battery fluid,—was, speaking in general terms, the distinguishing feature of the Brush invention. The drawings of the patent show a plain plate, and also corrugated, ribbed, slotted, honeycombed, and studded plates of various forms. The first conception of Brush was a plain plate of lead coated with lead oxide, which was retained in position by a sheet of paper or felt, which was secured to the plate by strips of wood.

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Bluebook (online)
52 F. 130, 2 C.C.A. 682, 1892 U.S. App. LEXIS 1385, Counsel Stack Legal Research, https://law.counselstack.com/opinion/electrical-accumulator-co-v-brush-electric-co-ca2-1892.