Bakelite Corp. v. Brunswick-Balke-Collender Co.

7 F.2d 697, 1925 U.S. Dist. LEXIS 1267
CourtDistrict Court, D. Delaware
DecidedAugust 12, 1925
DocketNo. 537
StatusPublished
Cited by1 cases

This text of 7 F.2d 697 (Bakelite Corp. v. Brunswick-Balke-Collender Co.) is published on Counsel Stack Legal Research, covering District Court, D. Delaware primary law. Counsel Stack provides free access to over 12 million legal documents including statutes, case law, regulations, and constitutions.

Bluebook
Bakelite Corp. v. Brunswick-Balke-Collender Co., 7 F.2d 697, 1925 U.S. Dist. LEXIS 1267 (D. Del. 1925).

Opinion

MORRIS, District Judge.

The Brunswick-Balke-Collender Company, defendant herein, manufactures billiard halls. The ingredients of the balls consist of a hinder and filler. With the filler we are but little concerned. The binder, however, is a phenolic condensation product — a condensed or dehydrated product resulting from the reaction of phenol and formaldehyde upon each other -and Bakelite Corporation, the plaintiff, alleges that, in, tho manufacture of halls containing that binder, the defendant employs the process of claims Nos. 1, 2, and 4 of plaintiff’s patent, No. 942,699, “for improvements in methods of making insoluble condensation products of phenol and formaldehyde” and tho process of claims Nos. 1, 5, and 6 of plaintiff’s patent No. 942,809 and, as well, that tho finished hall is the product called for by product claims Nos. 7 and 8 of the latter patent which is for an “improved method of reacting with formaldehyde upon phenol or a phenolic body, and this improved product resulting from such reaction.” Tho defenses are noninfringement, in that the defendant has kept wholly within the prior art and that, consequently, if and so far as plaintiff’s claims embrace defendant’s process or product, they are invalid, because of tho prior art.

The former of these patents,, No. 942,699, known as the “heat and pressure” patent, was granted December 7, 1909, upon an application filed July 3, 1907. With respect to the process of this patent, the patentee, Dr. Leo H. Backeland, at page 1, linos 29-37, says: “In practicing the invention, I react upon a phenolic body with formaldehyde to obtain a reaction product which is capable of transformation by heat into an insoluble and infusible body, and then convert this reaction, product, either alone or compounded with a suitable filling material, into such insoluble and infusible body by the combined action of heat and pressure.”

Claim, 1 may be considered typical of the claims of this patent in suit. It is: “1. The method of producing a hard, compact, insol[698]*698uble, and infusible condensation product of phenols and formaldehyde, which consists in reacting upon a phenolic body with formaldehyde, and then converting the product into a hard, insoluble, and infusible body by the combined action of heat and pressure.”

Patent No. 942,809, known as the “base” or “base-condensing agent” patent, was granted December 7, 1900, to Dr. Leo H. Baekeland upon an application filed October. 15, 1907. It states that condensation products had been prepared by simple boiling or heating of phenol and formaldehyde, but that the reaction proceeds very slowly unless to the mixture of the two there is added a third ingredient — a catalytic or condensing agent — to facilitate and expedite the reaction (page 1, lines 18-26); that acids and salts (page 1, lines 29, 30), .and large amounts of bases such as caustic soda, with subsequent neutralization by means of acid, had been used as condensing agents (page 2, line 127, to page 3, line 5); that, if large amounts of caustic soda are used, alkaline derivates of phenol-alcohol are obtained (page 1, lines 104-107); and that the proportion of bases used as condensing agents has a preponderant influence on the nature of the ultimate products (page 1, lines OS-OS). With respect to his achievements, covered ‘by this patent, the patentee says (page 1, lines 38-46): “I have discovered that the addition in proper proportions of an organic or inorganic base to a mixture of phenol and formaldehyde, or to either component of the mixture, facilitates the reaction and yields products which are commercially far superior to those obtained by simple heating or by the use of acids or salts as condensing agents.” By the claims the proportion or amount of base is fixed at not exceeding one-fifth of the equimolecular proportion of phenolic body employed. Claims typical of the method and product claims in suit of this patent are Nos. 1 and 8, respectively, which read thus:

“1. The method which consists in reacting on a phenolic body with formaldehyde in presence of a base serving as a condensing agent, the proportion of base in the product being less than one-fifth of the equimoleeular proportion of the phenolic body used.”
“8. The herein described condensation product resulting from the reaction of a phenolic body and formaldehyde in presence of a basic condensing agent, said eondensartion product characterized by its hardness, its insolubility in water and all known solvents, by its infusibility or resistance to heat, and by the presence therein of a proportion of free or combined base not exceeding one-fifth of the equimolecular proportion of phenolic body employed.”

The defendant’s process consists of several steps. To a mixture of equal portions of phenol and commercial (40 per cent.) formaldehyde it adds a base (caustic soda) in an amount equal to about 70 per cent, of the equimolecular proportion of the phenolic body used. The mixture is allowed to stand for some time. A measured quantity of the mixture is then put in a flask. The flask containing the desired quantity of the mixture is connected with a reflux condenser. The contents of the flask are heated to the boiling point, acquiring a reddish brown color, and are then poured into a bowl. Immediately the operator begins adding hydrochloric acid and stirring the mixture vigorously. This is continued until the mixture begins to separate into two liquids. One of these liquids is an aqueous solution, sometimes called “mother liquor,” and consists of the free water in the phenol and formaldehyde solution and also of the water which constitutes one of the products of the reaction. The second or remaining liquid is the other product of the reaction — the condensation product in its initial form. It is light brown in color and oily or viscous in character. The beginning of the separation of the two liquids is evidenced'by the appearance of drops of the oily liquid upon the surface of the then milky, opaque contents of the bowl. Thereafter the addition of hydrochloric acid and the stirring are cautiously continued until the separation of the contents is practically complete and the condensation product, now almost entirely at the surface, is caused to boil and bubble by the heat generated by the reaction. The reaction, shown by the boiling to have proceeded far enough, is then checked by the addition of water. The mother liquor soon rises to the top and isi poured off. The condensation product, then a hot, white, or creamy semiplastie mass, remains. The filler is added and intermixed, and the whole made into a small “pat.” The pats remain overnight' in the room in which they are made, and are then put into a drying room having a temperature of 160°-200° F., where they stay for 36 hours. After being in the drying room 8 hours, they are coarsely ground. Fourteen hours later the coarsely ground material is reground. At the end of the remaining period of fourteen hours in the drying room the dried material is put into molds and heated, under pressure of [699]*6993,500-4,000 pounds per square inch, for 45 minutes at a temperature of about 300° F. in a preforming press. Upon tbe removal of the balls from the molds they are again subjected to- heat and pressure — gunning—■ of 3,600-4,000 pounds per square inch for 35 minutes at a temperature of 340° F. in the Hyatt hydraulic gun described in Hyatt patent, No. 239,791, of 1881.

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Bluebook (online)
7 F.2d 697, 1925 U.S. Dist. LEXIS 1267, Counsel Stack Legal Research, https://law.counselstack.com/opinion/bakelite-corp-v-brunswick-balke-collender-co-ded-1925.