Application of Francis J. Honn and Willard M. Sims

364 F.2d 454, 53 C.C.P.A. 1469, 150 U.S.P.Q. (BNA) 652, 1966 CCPA LEXIS 334
CourtCourt of Customs and Patent Appeals
DecidedAugust 4, 1966
DocketPatent Appeal 7593
StatusPublished
Cited by12 cases

This text of 364 F.2d 454 (Application of Francis J. Honn and Willard M. Sims) is published on Counsel Stack Legal Research, covering Court of Customs and Patent Appeals primary law. Counsel Stack provides free access to over 12 million legal documents including statutes, case law, regulations, and constitutions.

Bluebook
Application of Francis J. Honn and Willard M. Sims, 364 F.2d 454, 53 C.C.P.A. 1469, 150 U.S.P.Q. (BNA) 652, 1966 CCPA LEXIS 334 (ccpa 1966).

Opinion

KIRKPATRICK, Judge.

This is an appeal from the decision of the Board of Appeals which affirmed the examiner’s rejection of claims 1-12 and 14-22 in appellants’ application 1 entitled “Fluorinated Elastomers and Method for Crosslinking Same.”

A short chronology of the proceedings leading to this appeal will be helpful in understanding the issues involved. Appellants’ 1953 parent application, like the present application, describes certain linear, elastomeric, fluorinated copolymers and methods for vulcanizing or cross-linking those polymers to produce products of increased toughness and heat resistance, and lessened plasticity and solubility. According to appellants, the parent application has issued as U. S. Patent No. 2,965,619 with claims drawn to vulcanized elastomers and processes of *456 preparing them from the linear, fluorinated copolymers.

The present application was originally filed with 13 claims drawn to certain of the vulcanizable elastomeric fluorinated copolymers disclosed therein. The examiner finally rejected all claims (now present claims 1-12 and 14-16) as based on an insufficient disclosure and as unpatentable over two prior art patents 2 to Dittman. Appellants appealed to the board; before its decision, the examiner reopened prosecution, citing a third patent to Rexford 3 against the claims. Appellants responded to that rejection by copying claims 1, 2 and 6-9 of Rexford into their application as present claims 17-22 and requested an interference be declared with Rexford. The examiner refused to institute interference proceedings, and entered a second final rejection of all claims, including claims 17-22, “as based on an insufficient disclosure,” “as being substantially met by Rexford” and “as unpatentable over either of the.Dittman * * * patents.” A second appeal to the board ensued. In his Answer, the examiner modified his position to the extent that, in addition to the insufficient disclosure rejection of all claims, claims 1-3, 5, 6, 8, 12, 14 and 17-22 were rejected as “fully met” by Rexford and claims 1-3, 5-9, 12, 14 and 17-22 4 were rejected “as unpatentable over” the Dittman patents. The board affirmed on all grounds. We shall consider each issue separately.

The “Insufficient Disclosure” Rejection

The appropriate starting point for disposition of the issue of sufficiency of disclosure is appellants’ specification. The portions which are relevant to the claimed subject matter are set out below:

These and other objects are accomplished by the following invention. Linear elastomers comprising disordered, saturated, fluorinated carbon chains, and including a substantial number of carbon atoms which are linked only to hydrogen and to other carbon atoms, are reacted with a crosslinking agent at elevated temperatures to produce a vulcanized elastomer. Ordinarily, the linear elastomer is at least 10 per cent comprised of -CH2- groups.

Disorder in the linear, saturated, fluorinated carbon chains is ordinarily achieved by the copolymerization of at least two mono-olefinic compounds. In order to obtain chemical stability in the elastomer at least one of the mono-olefinic compounds must be fluorinated. In order that the copolymer be elastomeric in nature, at least one of the mono-olefinic compounds must contain at least one carbon atom linked only to hydrogen and carbon atoms. At least 10 per cent of the carbon atoms in the chain must be of this type in order to obtain an elastomeric product. Ordinarily, a mono-olefinic compound containing a CH2= group is used and this results in the linear chains containing -CH2- groups. When the mono-olefinic compound contains an unsaturated chain of three or more carbon *457 atoms, methyl groups may be present and these remain as side groups on the linear chain.

Among the fluorinated mono-olefinic compounds which may be used as comonomers to produce fluorine-containing elastomers are:

These fluorinated mono-olefinic compounds may be copolymerized with each other, provided at least one of the comonomers contains at least one carbon atom bonded only to hydrogen and carbon atoms. Fluorinated olefinic compounds, such as those listed above, may also be copolymerized with other mono-olefinic compounds supplying the carbon atoms which are linked only to hydrogen and carbon atoms. Among the mono-olefinic compounds which may be used for this purpose are vinyl chloride, propylene, styrene, vinylidene, chloride, acrylonitrile, (n) butyl' acrylate, divinyl benzene, ethylene, acrylamide and vinyl bromide.

Among the copolymer systems which are particularly advantageous are the following:

*458 The copolymerization reaction may be carried out in either a water suspension type system or in a mass polymerization system. In the former system the reaction is preferably carried out at a temperature between about 0° C. and about 35° C. In a mass polymerization system the reaction is preferably carried out at a temperature between about -20° C. and about 0° C. With the water suspension type system a redox catalyst system is preferred. It has and contains an oxidant, a reductant and a variable valence metal salt. The oxidant in the water suspension type recipe is preferably an inorganic persulfate, such as potassium persulfate, sodium persulfate or ammonium persulfate, the latter being most desirable. The reductant is preferably a bisulfite, such as sodium bisulfite or potassium bisulfite, and preferably the former. The variable valence metal salt which is employed for the purpose of regenerating the oxidant is preferably in the form of an iron salt, such as ferrous sulfate or ferrous nitrate with ferrous sulfate being the most desirable variable valence metal salt.

In the mass polymerization system, organic peroxide promoters, and particularly halogen-substituted acyl peroxide, are used. Trichloroacetyl peroxide is a preferred promoter of this type. Other halogen-substituted organic peroxides suitable for carrying out the polymerization are trifluoroacetyl peroxide, difluoroacetyl peroxide, 2,4-dichlorobenzoyl peroxide, chloroacetyl peroxide, trifluorodiehloropropionyl peroxide, and dichlorofluoroacetyl peroxide.

The appealed claims are all directed to certain copolymers derived from a fluorohalogenated propylene and a fluorinated ethylene. Appellants and the Patent Office agree that only the compounds marked by an asterisk (*) in the above list of proposed “copolymer systems” fall within the scope of the appealed claims, of which claims 1, 8, 10, 15 and 17 are representative:

1.

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364 F.2d 454, 53 C.C.P.A. 1469, 150 U.S.P.Q. (BNA) 652, 1966 CCPA LEXIS 334, Counsel Stack Legal Research, https://law.counselstack.com/opinion/application-of-francis-j-honn-and-willard-m-sims-ccpa-1966.