Application of Alfred F. Steinhauer and Joseph C. Valenta

410 F.2d 411, 56 C.C.P.A. 1093
CourtCourt of Customs and Patent Appeals
DecidedMay 15, 1969
DocketPatent Appeal 8067
StatusPublished
Cited by1 cases

This text of 410 F.2d 411 (Application of Alfred F. Steinhauer and Joseph C. Valenta) is published on Counsel Stack Legal Research, covering Court of Customs and Patent Appeals primary law. Counsel Stack provides free access to over 12 million legal documents including statutes, case law, regulations, and constitutions.

Bluebook
Application of Alfred F. Steinhauer and Joseph C. Valenta, 410 F.2d 411, 56 C.C.P.A. 1093 (ccpa 1969).

Opinion

RICH, Judge.

This appeal is from the decision of the Patent Office Board of Appeals, adhered to on reconsideration, affirming the rejection of claims 1-18 of application serial No. 289,391, filed June 20, 1963, entitled “Akylhalodiphenyl Oxide Sulfonates.” No claim is allowed.

The claimed invention, defined in various ways in different claims, is mixtures of compounds. The nucleus of these compounds is diphenyl oxide. To the nucleus is attached one alkyl radical having from 12 to 22 carbon atoms, one or two halogens other than fluorine, and one or two sulfonic acid or sulfonate radicals. They can be visualized by the following modification of a chart used by appellants at argument:

wherein M is a water-solubilizing cation, more particularly defined in the specification as follows:

* * * wherever M is used, the cation is present in sufficient quantity to satisfy the valence of the sulfonate radical with which it is associated. Thus, in the radical -SO3M, it is to be understood that M represents 1 molar proportion of a mono-valent cation, % molar proportion of a divalent cation or 1/3 molar proportion of a trivalent cation.

Appellants may produce their mixtures by starting with diphenyl oxide and halogenating, alkylating, and sulfon-ating it in any desired sequence, according to known procedures, thus producing a mixture of sulfonic acids. The latter may be converted to any desired salt thereof by reaction with the appropriate base or salt. It is also disclosed that either or both of the benzene rings of the diphenyl oxide may be alkylated or halogenated before being condensed to form the diphenyl oxide nucleus.

*413 The principal problem in this ease derives from the fact that appellants do not disclose the position of all of the substituents — i.e., the alkyl, halogen, and sulfonate — for any one specific compound. While some positions are mentioned as to some compounds, appellants clearly are not concerned with producing specific compounds nor with the positioning of the substituents on the nucleus.

Appellants’ brief refers, inter alia, to the following passage from the specification on this point;

It is readily apparent that in the synthesis of the compounds of the invention one may, and usually does, obtain a mixture of cogeneric products wherein the number of alkyl, halogen or sulfonate substituents on the- diphenyl oxide nucleus has an average value other than the whole numbers 1 or 2. Thus, a typical product may contain an average of 1.1 alkyl groups, 1.8 halogen atoms and 1.4 sulfonate groups. Such mixtures are in general fully as useful as the pure compounds and are sometimes actually preferred to the latter. 1

Commenting further, the brief says:

* * * the product made by any particular process will in general be a co-generic mixture of isomers and analogs having in general the same basic properties and uses as -the individual components thereof.

The specification appears to bear this out and says, with respect to uses, that the mixtures, resulting from the process generally described and as exemplified in numerous examples, are highly surface-active, are useful as detergents, wetting agents, emulsifying and dispersing agents, corrosion inhibitors, and oil-soluble surfactants and have the additional desirable properties of inhibiting the growth of bacteria and fungi. Lengthy descriptions of specific uses in the laundry and dry cleaning industries with cleaning tests are included as well as tests of bacteriostatic and fungistatic effects both on materials and, in the form of medical soaps, on humans. Uses are also described in agriculture and paper pulp manufacture. Utility is not questioned, and patentability is in no wise dependent on utility or proof of unexpected advantageous properties. There is no issue of novelty, and no prior art reference is relied on.

Representative claims read:

1. A cogeneric mixture of alkylat-ed, halogenated, sulfonated diphenyl oxide wherein there is one alkyl radical, and it contains 12 to 22 carbon atoms; one to two halogen atoms, and they have atomic numbers from 17 to 53; and one to two sulfonate groups.
3. A cogeneric mixture of compounds corresponding to the formula *414 wherein R is an alkyl radical containing 12 to 22 carbon atoms; X is a halogen having an atomic number from 17 to 53; m and n are integers from 1 to 2; and, M is a water-solu-bilizing cation.

*413

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Related

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439 F.2d 1232 (Customs and Patent Appeals, 1971)

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Bluebook (online)
410 F.2d 411, 56 C.C.P.A. 1093, Counsel Stack Legal Research, https://law.counselstack.com/opinion/application-of-alfred-f-steinhauer-and-joseph-c-valenta-ccpa-1969.